Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 16.8, Problem 20ATS
Interpretation Introduction
Interpretation: Structure for the given molecular formula
Concept Introduction HDI (Index of hydrogen deficiency): HDI values gives information on the level of unsaturation (means a double bond or a ring) on the structure of the compound.
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2. Write a complete mechanism for the reaction shown below.
NaOCH
LOCH₁
O₂N
NO2
CH₂OH, 20 °C
O₂N
NO2
4. Propose a synthesis of the target molecules from the respective starting materials.
a)
b)
LUCH
C
Br
OH
The following mechanism for the gas phase reaction of H2 and ICI that is consistent with the observed rate
law is:
step 1
step 2
slow: H2(g) +ICI(g) → HCl(g) + HI(g)
fast: ICI(g) + HI(g) → HCl(g) + |2(g)
(1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is
not needed, leave it blank.
+
→
+
(2) Which species acts as a catalyst? Enter formula. If none, leave box blank:
(3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank:
(4) Complete the rate law for the overall reaction that is consistent with this mechanism.
(Use the form k[A][B]"..., where '1' is understood (so don't write it) for m, n etc.)
Rate =
Chapter 16 Solutions
Organic Chemistry, Binder Ready Version
Ch. 16.4 - Prob. 1LTSCh. 16.4 - Prob. 1PTSCh. 16.4 - Prob. 2ATSCh. 16.4 - Prob. 3ATSCh. 16.4 - Prob. 2LTSCh. 16.4 - Prob. 4PTSCh. 16.4 - Prob. 5ATSCh. 16.4 - Prob. 6ATSCh. 16.5 - Prob. 3LTSCh. 16.5 - Prob. 7PTS
Ch. 16.5 - Prob. 8ATSCh. 16.5 - Prob. 9ATSCh. 16.5 - Prob. 10CCCh. 16.6 - Prob. 4LTSCh. 16.6 - Prob. 11PTSCh. 16.6 - Prob. 12PTSCh. 16.6 - Prob. 13PTSCh. 16.6 - Prob. 14ATSCh. 16.7 - Prob. 5LTSCh. 16.7 - Prob. 15PTSCh. 16.7 - Prob. 16ATSCh. 16.7 - Prob. 17CCCh. 16.7 - Prob. 18CCCh. 16.8 - Prob. 6LTSCh. 16.8 - Prob. 19PTSCh. 16.8 - Prob. 20ATSCh. 16.9 - Prob. 7LTSCh. 16.9 - Prob. 21PTSCh. 16.9 - Prob. 22ATSCh. 16.10 - Prob. 8LTSCh. 16.10 - Prob. 23PTSCh. 16.10 - Prob. 24ATSCh. 16.12 - Prob. 9LTSCh. 16.12 - Prob. 25PTSCh. 16.12 - Prob. 26ATSCh. 16.12 - Prob. 27ATSCh. 16.13 - Prob. 10LTSCh. 16.13 - Prob. 28PTSCh. 16.13 - Prob. 29PTSCh. 16.13 - Prob. 30ATSCh. 16 - Prob. 31PPCh. 16 - Prob. 32PPCh. 16 - Prob. 33PPCh. 16 - Prob. 34PPCh. 16 - Prob. 35PPCh. 16 - Prob. 36PPCh. 16 - Prob. 37PPCh. 16 - Prob. 38PPCh. 16 - Prob. 39PPCh. 16 - Prob. 40PPCh. 16 - Prob. 41PPCh. 16 - Prob. 42PPCh. 16 - Prob. 43PPCh. 16 - Prob. 44PPCh. 16 - Prob. 45PPCh. 16 - Prob. 46PPCh. 16 - Prob. 47PPCh. 16 - Prob. 48PPCh. 16 - Prob. 49PPCh. 16 - Prob. 50PPCh. 16 - Prob. 51PPCh. 16 - Prob. 52PPCh. 16 - Prob. 53PPCh. 16 - Prob. 54PPCh. 16 - Prob. 55PPCh. 16 - Prob. 56PPCh. 16 - Prob. 57PPCh. 16 - Prob. 58PPCh. 16 - Prob. 59PPCh. 16 - Prob. 60PPCh. 16 - Prob. 61PPCh. 16 - Prob. 62IPCh. 16 - Prob. 63IPCh. 16 - Prob. 64IPCh. 16 - Prob. 65IPCh. 16 - Prob. 66IPCh. 16 - Prob. 67IPCh. 16 - Prob. 68IPCh. 16 - Prob. 69IPCh. 16 - Prob. 70IPCh. 16 - Prob. 71IP
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