The given compounds to be distinguished using both 13 C NMR and 1 H NMR spectroscopy. Concept Introduction : Both 13 C NMR and 1 H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1 H NMR , the number of signals generated in 13 C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13 C − 13 C nuclei are weakly involved due to the low abundance of 13 C isotopes of carbon atom.

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Answer 1

Question

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

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21. Zn Cl₂→ ZnCl2 22. ZnCO3 ZnO CO₂ 23. Mg + Sg MgS 24. Fe + Cl₂ FeCl3 25. Ag + S8 Ag₂S 26. K S8 K₂S 27. Al HCI AlCl3 H2 28. Mg H3PO4 Mg3(PO4)2 + H₂ 29. Cu + AgNO3 Cu(NO3)2 + Ag 30. Al + Pb(NO3)2 Pb + Al(NO3)3 31. Zn + Sn(NO3)4 Zn(NO3)2 Sn 32. Cl2 + All 3 AlCl3 _ 12 33. Br2 + Cul CuBr 12 34. KBr + Pb(NO3)2 KNO3 PbBr2 These next ones have an element shared between two different compounds. The Total amount in the Reactatnt still needs to equal the total amount in the product. 35.H₂O2 ← H₂O + 0₂ 36. C₂Ho CO2 + H₂O 37. Zn + HCI → ZnCl+ H₂ 38. NH3 + _HCl → NH.C 39. Mg(OH)2 + H3PO4 → H₂O+ Mg3(PO4)2 40. NHẠOH + FeCl3 NH4Cl + Fe(OH)3

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Answer 2

Question

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

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Answer 3

Question

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

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Answer 4

Question

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

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Answer 5

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 6

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 7

Chapter 16, Problem 38PP

(a)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 8

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 9

(b)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 10

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 11

(c)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 12

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 13

(d)

Interpretation Introduction

Interpretation: The given compounds to be distinguished using both 13C NMR and 1H NMR spectroscopy.

Concept Introduction:

Both 13C NMR and 1H NMR spectroscopy gives information on the different electronic environments of carbon and protons respectively. As like 1H NMR , the number of signals generated in 13C NMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C−13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 16.4 - Prob. 1LTS Ch. 16.4 - Prob. 1PTS Ch. 16.4 - Prob. 2ATS Ch. 16.4 - Prob. 3ATS Ch. 16.4 - Prob. 2LTS Ch. 16.4 - Prob. 4PTS Ch. 16.4 - Prob. 5ATS Ch. 16.4 - Prob. 6ATS Ch. 16.5 - Prob. 3LTS Ch. 16.5 - Prob. 7PTS

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