Student Study Guide and Solutions Manual T/A Organic Chemistry
Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Chapter 16.4, Problem 1LTS
Interpretation Introduction

Interpretation: The given red protons are whether homotopic, Enantiotopic or Diastereotopic to be predicted.

Concept Introduction:

Homotopic: If the protons are interchangeable through rotational symmetry, then the protons are chemically equivalent and termed as homotopic.

Enantiotopic:  If the protons are interchangeable through reflectional symmetry, then the protons are chemically equivalent and termed as Enantiotopic.

Diastereotopic: If the protons are not interchangeable through either of the symmetry operations, then the protons are Diastereotopic; the protons are not chemically equivalent if a chiral center present in the molecule.

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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

Chapter 16 Solutions

Student Study Guide and Solutions Manual T/A Organic Chemistry

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