Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Chapter 16.4, Problem 6ATS
Interpretation Introduction
Interpretation: The structure of given molecular formula and the total number of proton signals should be identified.
Concept Introduction:
1H NMR: A technique gives information to predict the Carbon and Hydrogen connectivity in the organic compounds.
HDI (Index of hydrogen deficiency): HDI values gives information on the level of unsaturation (means a double bond or a ring) on the structure of the compound.
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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless
otherwise noted.
a)
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BH3 •THF
b)
1) NaOH
2) H3O+
solve
d)
ala
1) EtMgBr
2) H3O+
e)
H2N
سكر
CuLi
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1) SOCI2
2) EtMgBr
3) H3O+
NC
H3O+
Δ
There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:
QUESTION: Summarise and report these results including an indication of measurement uncertainty.
In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).
Mass of Taurine (mg)
Mass of Taurine (mg)
(Table continued)
152.01
152.23
151.87
151.45
154.11
152.64
152.98
153.24
152.88
151.45
153.49
152.48
150.68
152.33
151.52
153.63
152.48
151.68
153.17
153.40
153.77
153.67
152.34
153.16
152.57
153.02
152.86
151.50
151.23
152.57
152.72
151.54
146.47
152.38
152.44
152.54
152.53
152.54
151.32…
Indicate the rate expressions for reactions that have order 0, 1, and 2.
Chapter 16 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
Ch. 16.4 - Prob. 1LTSCh. 16.4 - Prob. 1PTSCh. 16.4 - Prob. 2ATSCh. 16.4 - Prob. 3ATSCh. 16.4 - Prob. 2LTSCh. 16.4 - Prob. 4PTSCh. 16.4 - Prob. 5ATSCh. 16.4 - Prob. 6ATSCh. 16.5 - Prob. 3LTSCh. 16.5 - Prob. 7PTS
Ch. 16.5 - Prob. 8ATSCh. 16.5 - Prob. 9ATSCh. 16.5 - Prob. 10CCCh. 16.6 - Prob. 4LTSCh. 16.6 - Prob. 11PTSCh. 16.6 - Prob. 12PTSCh. 16.6 - Prob. 13PTSCh. 16.6 - Prob. 14ATSCh. 16.7 - Prob. 5LTSCh. 16.7 - Prob. 15PTSCh. 16.7 - Prob. 16ATSCh. 16.7 - Prob. 17CCCh. 16.7 - Prob. 18CCCh. 16.8 - Prob. 6LTSCh. 16.8 - Prob. 19PTSCh. 16.8 - Prob. 20ATSCh. 16.9 - Prob. 7LTSCh. 16.9 - Prob. 21PTSCh. 16.9 - Prob. 22ATSCh. 16.10 - Prob. 8LTSCh. 16.10 - Prob. 23PTSCh. 16.10 - Prob. 24ATSCh. 16.12 - Prob. 9LTSCh. 16.12 - Prob. 25PTSCh. 16.12 - Prob. 26ATSCh. 16.12 - Prob. 27ATSCh. 16.13 - Prob. 10LTSCh. 16.13 - Prob. 28PTSCh. 16.13 - Prob. 29PTSCh. 16.13 - Prob. 30ATSCh. 16 - Prob. 31PPCh. 16 - Prob. 32PPCh. 16 - Prob. 33PPCh. 16 - Prob. 34PPCh. 16 - Prob. 35PPCh. 16 - Prob. 36PPCh. 16 - Prob. 37PPCh. 16 - Prob. 38PPCh. 16 - Prob. 39PPCh. 16 - Prob. 40PPCh. 16 - Prob. 41PPCh. 16 - Prob. 42PPCh. 16 - Prob. 43PPCh. 16 - Prob. 44PPCh. 16 - Prob. 45PPCh. 16 - Prob. 46PPCh. 16 - Prob. 47PPCh. 16 - Prob. 48PPCh. 16 - Prob. 49PPCh. 16 - Prob. 50PPCh. 16 - Prob. 51PPCh. 16 - Prob. 52PPCh. 16 - Prob. 53PPCh. 16 - Prob. 54PPCh. 16 - Prob. 55PPCh. 16 - Prob. 56PPCh. 16 - Prob. 57PPCh. 16 - Prob. 58PPCh. 16 - Prob. 59PPCh. 16 - Prob. 60PPCh. 16 - Prob. 61PPCh. 16 - Prob. 62IPCh. 16 - Prob. 63IPCh. 16 - Prob. 64IPCh. 16 - Prob. 65IPCh. 16 - Prob. 66IPCh. 16 - Prob. 67IPCh. 16 - Prob. 68IPCh. 16 - Prob. 69IPCh. 16 - Prob. 70IPCh. 16 - Prob. 71IP
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- 1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.arrow_forward3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗarrow_forward2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward
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