Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Question
Chapter 16.3, Problem 28PP
Interpretation Introduction
To Determine:
- Millicurie of technetium-99 m should be given to a 50.0 kg person.
- Equivalent dose in millisieverts.
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 16 Solutions
Basic Chemistry
Ch. 16.1 - Prob. 1PPCh. 16.1 - Prob. 2PPCh. 16.1 - Naturally occurring potassium consists of three...Ch. 16.1 - Prob. 4PPCh. 16.1 - Prob. 5PPCh. 16.1 - Prob. 6PPCh. 16.1 - Prob. 7PPCh. 16.1 - Prob. 8PPCh. 16.1 - Supply the missing information in the following...Ch. 16.1 - Prob. 10PP
Ch. 16.1 - Prob. 11PPCh. 16.1 - Prob. 12PPCh. 16.2 - Prob. 13PPCh. 16.2 - Prob. 14PPCh. 16.2 - Prob. 15PPCh. 16.2 - Prob. 16PPCh. 16.2 - Prob. 17PPCh. 16.2 - Prob. 18PPCh. 16.2 - Prob. 19PPCh. 16.2 - Prob. 20PPCh. 16.2 - Prob. 21PPCh. 16.2 - Prob. 22PPCh. 16.3 - Prob. 23PPCh. 16.3 - Prob. 24PPCh. 16.3 - Prob. 25PPCh. 16.3 - Prob. 26PPCh. 16.3 - Prob. 27PPCh. 16.3 - Prob. 28PPCh. 16.4 - Prob. 29PPCh. 16.4 - Prob. 30PPCh. 16.4 - Prob. 31PPCh. 16.4 - Prob. 32PPCh. 16.4 - Prob. 33PPCh. 16.4 - Prob. 34PPCh. 16.5 - Prob. 35PPCh. 16.5 - Prob. 36PPCh. 16.5 - Prob. 37PPCh. 16.5 - Prob. 38PPCh. 16.5 - Prob. 39PPCh. 16.5 - Prob. 40PPCh. 16.6 - Prob. 41PPCh. 16.6 - Prob. 42PPCh. 16.6 - Prob. 43PPCh. 16.6 - Prob. 44PPCh. 16.6 - Prob. 45PPCh. 16.6 - Prob. 46PPCh. 16.6 - Prob. 47PPCh. 16.6 - Prob. 48PPCh. 16.6 - Prob. 49PPCh. 16.6 - Prob. 50PPCh. 16 - Prob. 51UTCCh. 16 - Prob. 52UTCCh. 16 - The chapter sections to review are shown in...Ch. 16 - Prob. 54UTCCh. 16 - Prob. 55UTCCh. 16 - Prob. 56UTCCh. 16 - Prob. 57APPCh. 16 - Prob. 58APPCh. 16 - Prob. 59APPCh. 16 - Prob. 60APPCh. 16 - Prob. 61APPCh. 16 - Prob. 62APPCh. 16 - Prob. 63APPCh. 16 - Prob. 64APPCh. 16 - Prob. 65APPCh. 16 - Prob. 66APPCh. 16 - Prob. 67APPCh. 16 - Prob. 68APPCh. 16 - Prob. 69APPCh. 16 - Prob. 70APPCh. 16 - Prob. 71APPCh. 16 - Prob. 72APPCh. 16 - Prob. 73APPCh. 16 - Prob. 74APPCh. 16 - Prob. 75APPCh. 16 - Prob. 76APPCh. 16 - Prob. 77APPCh. 16 - Prob. 78APPCh. 16 - Prob. 79CPCh. 16 - Prob. 80CPCh. 16 - Prob. 81CPCh. 16 - Prob. 82CPCh. 16 - Prob. 83CPCh. 16 - Prob. 84CPCh. 16 - Prob. 85CPCh. 16 - Prob. 86CPCh. 16 - Prob. 87CPCh. 16 - Prob. 88CPCh. 16 - Prob. 89CPCh. 16 - Prob. 90CPCh. 16 - Consider the reaction of sodium oxalate (Na2C2O4)...Ch. 16 - Prob. 34CICh. 16 - Prob. 35CICh. 16 - Prob. 36CICh. 16 - Prob. 37CICh. 16 - Prob. 38CICh. 16 - Prob. 39CICh. 16 - Prob. 40CI
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- Show the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forward
- Draw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forward
- what are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward
- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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