Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
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124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
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Chapter 16 Solutions
Basic Chemistry
Ch. 16.1 - Prob. 1PPCh. 16.1 - Prob. 2PPCh. 16.1 - Naturally occurring potassium consists of three...Ch. 16.1 - Prob. 4PPCh. 16.1 - Prob. 5PPCh. 16.1 - Prob. 6PPCh. 16.1 - Prob. 7PPCh. 16.1 - Prob. 8PPCh. 16.1 - Supply the missing information in the following...Ch. 16.1 - Prob. 10PP
Ch. 16.1 - Prob. 11PPCh. 16.1 - Prob. 12PPCh. 16.2 - Prob. 13PPCh. 16.2 - Prob. 14PPCh. 16.2 - Prob. 15PPCh. 16.2 - Prob. 16PPCh. 16.2 - Prob. 17PPCh. 16.2 - Prob. 18PPCh. 16.2 - Prob. 19PPCh. 16.2 - Prob. 20PPCh. 16.2 - Prob. 21PPCh. 16.2 - Prob. 22PPCh. 16.3 - Prob. 23PPCh. 16.3 - Prob. 24PPCh. 16.3 - Prob. 25PPCh. 16.3 - Prob. 26PPCh. 16.3 - Prob. 27PPCh. 16.3 - Prob. 28PPCh. 16.4 - Prob. 29PPCh. 16.4 - Prob. 30PPCh. 16.4 - Prob. 31PPCh. 16.4 - Prob. 32PPCh. 16.4 - Prob. 33PPCh. 16.4 - Prob. 34PPCh. 16.5 - Prob. 35PPCh. 16.5 - Prob. 36PPCh. 16.5 - Prob. 37PPCh. 16.5 - Prob. 38PPCh. 16.5 - Prob. 39PPCh. 16.5 - Prob. 40PPCh. 16.6 - Prob. 41PPCh. 16.6 - Prob. 42PPCh. 16.6 - Prob. 43PPCh. 16.6 - Prob. 44PPCh. 16.6 - Prob. 45PPCh. 16.6 - Prob. 46PPCh. 16.6 - Prob. 47PPCh. 16.6 - Prob. 48PPCh. 16.6 - Prob. 49PPCh. 16.6 - Prob. 50PPCh. 16 - Prob. 51UTCCh. 16 - Prob. 52UTCCh. 16 - The chapter sections to review are shown in...Ch. 16 - Prob. 54UTCCh. 16 - Prob. 55UTCCh. 16 - Prob. 56UTCCh. 16 - Prob. 57APPCh. 16 - Prob. 58APPCh. 16 - Prob. 59APPCh. 16 - Prob. 60APPCh. 16 - Prob. 61APPCh. 16 - Prob. 62APPCh. 16 - Prob. 63APPCh. 16 - Prob. 64APPCh. 16 - Prob. 65APPCh. 16 - Prob. 66APPCh. 16 - Prob. 67APPCh. 16 - Prob. 68APPCh. 16 - Prob. 69APPCh. 16 - Prob. 70APPCh. 16 - Prob. 71APPCh. 16 - Prob. 72APPCh. 16 - Prob. 73APPCh. 16 - Prob. 74APPCh. 16 - Prob. 75APPCh. 16 - Prob. 76APPCh. 16 - Prob. 77APPCh. 16 - Prob. 78APPCh. 16 - Prob. 79CPCh. 16 - Prob. 80CPCh. 16 - Prob. 81CPCh. 16 - Prob. 82CPCh. 16 - Prob. 83CPCh. 16 - Prob. 84CPCh. 16 - Prob. 85CPCh. 16 - Prob. 86CPCh. 16 - Prob. 87CPCh. 16 - Prob. 88CPCh. 16 - Prob. 89CPCh. 16 - Prob. 90CPCh. 16 - Consider the reaction of sodium oxalate (Na2C2O4)...Ch. 16 - Prob. 34CICh. 16 - Prob. 35CICh. 16 - Prob. 36CICh. 16 - Prob. 37CICh. 16 - Prob. 38CICh. 16 - Prob. 39CICh. 16 - Prob. 40CI
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- Label the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY