Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 16.2, Problem 16.4P
Show the product of the Diels-Alder dimerization of cyclobutadiene. (This reaction is similar to the dimerization of cyclopentadiene, discussed in Section15-11.)
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Directions: Given the following reaction and the stress applied in each
reaction, answer the question below.
A. H2(g) + Cl2(g) 2 HCl(g)
Stress applied: Decreasing the pressure
1. What is the Keq expression?
2. What will be the effect in the number of moles of HCl(g)?
3. What will be the Equilibrium Shift or the reaction?
B.
Fe3O4(s) + 4 H2(g) + heat 53 Fe(s) + 4 H₂O(g)
Stress applied: Increasing the temperature
1. What is the Keq expression?.
2. What will be the effect in the volume of water vapor collected?
3. What will be the Equilibrium Shift or the reaction?
C. 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g) + heat
Stress applied: Increasing the volume of the container
1. What is the Keq expression?.
2. What will be the effect in the amount of H₂O?
3. What will be the Equilibrium Shift or the reaction?
Consider the solubility products (Ksp values) for the following compounds:SrSO4 (Ksp = 7.6 x 10−7), BaSO4 (Ksp = 1.5 x 10−9), SrCO3 (Ksp = 7.0 x 10−10), BaCO3 (Ksp = 1.6 x 10−9)Which anion is the harder base, CO32− or SO42−? Justify your answer.
Q1:
a) Arrange the compounds in order of decreasing pKa, highest first.
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Chapter 16 Solutions
Organic Chemistry (9th Edition)
Ch. 16.2 - Prob. 16.1PCh. 16.2 - Prob. 16.2PCh. 16.2 - a. Draw the resonance forms of benzene,...Ch. 16.2 - Show the product of the Diels-Alder dimerization...Ch. 16.4 - Prob. 16.5PCh. 16.6 - Make a model of cyclooctatetraene in the tub...Ch. 16.6 - Prob. 16.7PCh. 16.6 - Prob. 16.8PCh. 16.7 - Prob. 16.9PCh. 16.8A - a. Draw the molecular orbitals for the...
Ch. 16.8A - Repeat Problem16-10 for the cyclopentadienyl ions....Ch. 16.8C - Explain why each compound or ion should be...Ch. 16.8C - The following hydrocarbon has an unusually large...Ch. 16.8C - Prob. 16.14PCh. 16.8C - Prob. 16.15PCh. 16.9B - Prob. 16.16PCh. 16.9C - Show which of the nitrogen atoms in purine are...Ch. 16.9C - The proton NMR spectrum of 2-pyridone gives the...Ch. 16.9D - Prob. 16.19PCh. 16.9D - Prob. 16.20PCh. 16.10 - Prob. 16.21PCh. 16.12 - Ciprofloxacin is a member of the fluoroquinolone...Ch. 16.13 - Draw and name all the chlorinated benzenes having...Ch. 16.13 - Name the following compounds:Ch. 16.15 - The UV spectrum of 1-phenylprop-2-en-1-ol shows an...Ch. 16 - Prob. 16.26SPCh. 16 - Name the following compounds:Ch. 16 - Draw and name all the methyl, dimethyl, and...Ch. 16 - Four pairs of compounds are shown. In each pair,...Ch. 16 - One of the following hydrocarbons is much more...Ch. 16 - In Kekuls time cyclohexane was unknown, and there...Ch. 16 - Prob. 16.32SPCh. 16 - Azulene is a deep-blue hydrocarbon with resonance...Ch. 16 - Prob. 16.34SPCh. 16 - Prob. 16.35SPCh. 16 - Prob. 16.36SPCh. 16 - Prob. 16.37SPCh. 16 - Prob. 16.38SPCh. 16 - Prob. 16.39SPCh. 16 - Biphenyl has the following structure. a. Is...Ch. 16 - Anions of hydrocarbons are rare, and dianions of...Ch. 16 - How would you convert the following compounds to...Ch. 16 - Prob. 16.43SPCh. 16 - Prob. 16.44SPCh. 16 - A student found an old bottle labeled thymol on...Ch. 16 - Prob. 16.46SPCh. 16 - Prob. 16.47SPCh. 16 - Prob. 16.48SPCh. 16 - The proton NMR chemical shifts of the hydrogens in...Ch. 16 - Prob. 16.50SPCh. 16 - NMR has been used to probe many molecular...
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