
(a)
Interpretation:
The delocalization of the positive charge, unpaired electron and negative charge of the benzyl cation, radical and anion using their resonance forms is to be drawn.
Concept introduction:
Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structures combine to give a resonance hybrid that is lower in energy and is the most stable structure.
(b)
Interpretation:
The information regarding the formation of benzyl bromide by the reaction between toluene and bromine in the presence of light is given. The mechanism for the given reaction is to be stated.
Concept introduction:
A free radical reaction occurs in the presence of UV light. It involves three steps initiation, propagation and termination reaction. The
(c)
Interpretation:
Two different types of reactions are given. The reaction that will have a faster rate and give better yield using the drawing of the transition state is to be stated.
Concept introduction:
Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structures combine to give a resonance hybrid that is lower in energy and is the most stable structure.

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Chapter 16 Solutions
Organic Chemistry (9th Edition)
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- Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)arrow_forwardHi I need help on the question provided in the image.arrow_forwardDraw a reasonable mechanism for the following reaction:arrow_forward
- Draw the mechanism for the following reaction: CH3 CH3 Et-OH Et Edit the reaction by drawing all steps in the appropriate boxes and connecting them with reaction arrows. Add charges where needed. Electron-flow arrows should start on the electron(s) of an atom or a bond and should end on an atom, bond, or location where a new bond should be created. H± EXP. L CONT. י Α [1] осн CH3 а CH3 :Ö Et H 0 N о S 0 Br Et-ÖH | P LL Farrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCl. What is the molarity of the HCl?arrow_forward20.00 mL of 0.025 M HCl is titrated with 0.035 M KOH. What volume of KOH is needed?arrow_forward
- 20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCl. What is the molarity of the HCl?arrow_forward20.00 mL of 0.025 M HCl is titrated with 0.035 M KOH. What volume of KOH is needed?arrow_forward20.00 mL of 0.150 M HCl is titrated with 37.75 mL of NaOH. What is the molarity of the NaOH?arrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

