Consider the equation ∆G = ∆G ° + RT ln( Q ). What is the value of ∆ G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = − RT ln( K ). When ∆ G ° > 0, what does it indicate about K ? When ∆G ° < 0, what does it indicate about K? When t ∆ G ° = 0, what does it indicate about K ? ∆G predicts spontaneity for a reaction, whereas ∆G ° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆ G ° to determine the spontaneity of a reaction?
Consider the equation ∆G = ∆G ° + RT ln( Q ). What is the value of ∆ G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = − RT ln( K ). When ∆ G ° > 0, what does it indicate about K ? When ∆G ° < 0, what does it indicate about K? When t ∆ G ° = 0, what does it indicate about K ? ∆G predicts spontaneity for a reaction, whereas ∆G ° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆ G ° to determine the spontaneity of a reaction?
Consider the equation ∆G = ∆G° + RT ln(Q). What is the value of ∆G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = −RT ln(K). When ∆G° > 0, what does it indicate about K? When ∆G° < 0, what does it indicate about K? When t ∆G° = 0, what does it indicate about K? ∆G predicts spontaneity for a reaction, whereas ∆G° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆G° to determine the spontaneity of a reaction?
Laser. Indicate the relationship between metastable state and stimulated emission.
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY