Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 16, Problem 87AP
. When hydrochloric acid, HCI. is added dropwise to a buffered solution, the ______component of the buffer consumes the added hydrogen ion.
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In general, adding a strong acid or a strong base to a buffer solution _________
neutralizes the solution making a solution that is neither acidic nor basic.
drastically changes the pH to be either strongly acidic or strongly basic.
causes only a slight change in pH making the solution only a little more acidic or only a little more basic than it already was.
has variable results so there is no general trend
A buffer is a solution that contains both an acid and a base. How can we prevent the acid and base from reacting with each
other?
O A. Since the acid is a weak acid, it will not react with the base.
O B. By using an conjugate acid-base pair, we can ensure they do not react with one another.
O C. The acid and base should be kept separate for as long as possible, and only mixed together at the last minute.
O D. Since the solution has a very low concentration, the acid and base will not react with one another.
Which theory or concept can explain buffer solution precisely? Explain your answer.
Chapter 16 Solutions
Introductory Chemistry: A Foundation
Ch. 16.1 - Exercise 16.1 Which of the following represent...Ch. 16.2 - Vinegar contains acetic acid and is used in salad...Ch. 16.3 - Exercise 16.2 Calculate [H+] in a solution in...Ch. 16.4 - Prob. 16.3SCCh. 16.4 - Prob. 1CTCh. 16.4 - Prob. 16.4SCCh. 16.4 - Exercise 16.5 The pH of rainwater in a polluted...Ch. 16.4 - Exercise 16.6 The pOH of a liquid drain cleaner...Ch. 16.5 - Exercise 16.7 Calculate the pH of a solution of...Ch. 16 - You are asked for the H+ concentration in a...
Ch. 16 - Explain why Cl- does not affect the pH of an...Ch. 16 - Write the general reaction for an acid acting in...Ch. 16 - Differentiate among the terms concentrated,...Ch. 16 - What is meant by “pH”? True or false: A strong...Ch. 16 - Consider two separate solutions: one containing a...Ch. 16 - Prob. 7ALQCh. 16 - Prob. 8ALQCh. 16 - Stanley’s grade-point average (GPA) is 3.28. What...Ch. 16 - Prob. 10ALQCh. 16 - . Mixing together aqueous solutions of acetic acid...Ch. 16 - Prob. 12ALQCh. 16 - . Consider the equation:...Ch. 16 - . Choose the answer that best completes the...Ch. 16 - Prob. 15ALQCh. 16 - . The following figures are molecular-level...Ch. 16 - Prob. 17ALQCh. 16 - What are some physical properties that...Ch. 16 - Write an equation showing how HCl(g) behaves as an...Ch. 16 - Prob. 3QAPCh. 16 - How do the components of a conjugate acid—base...Ch. 16 - 5. Given the general equation illustrating the...Ch. 16 - According to Arrhenius, ____________ produce...Ch. 16 - Which of the following do not represent a...Ch. 16 - Which of the following do not represent a...Ch. 16 - In each of the following chemical equations,...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - Prob. 13QAPCh. 16 - . Write the conjugate base for each of the...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . What does it mean to say that an acid is strong...Ch. 16 - Prob. 18QAPCh. 16 - . How is the strength of an acid related to the...Ch. 16 - . A strong acid has a weak conjugate base, whereas...Ch. 16 - . Write the formula for the hydronium ion. Write...Ch. 16 - Prob. 22QAPCh. 16 - . Organic acids contain the carboxyl group Using...Ch. 16 - Prob. 24QAPCh. 16 - 25. Which of the following acids have relatively...Ch. 16 - . The “Chemistry in Focus” segment Plants Fight...Ch. 16 - . Water is the most common amphoteric substance,...Ch. 16 - . Anions containing hydrogen (for example. HCO3and...Ch. 16 - . What is meant by the iou-product constant for...Ch. 16 - . What happens to the hydroxide ion concentration...Ch. 16 - Prob. 31QAPCh. 16 - Prob. 32QAPCh. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - 35. For each pair of concentrations, tell which...Ch. 16 - Prob. 36QAPCh. 16 - . Why do scientists tend to express the acidity of...Ch. 16 - . Using Fig. 16.3, list the approximate pH value...Ch. 16 - . For a hydrogen ion concentration of 2.33106M,...Ch. 16 - . The “Chemistry in Focus” segment Garden-Variety...Ch. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 42QAPCh. 16 - Prob. 43QAPCh. 16 - Prob. 44QAPCh. 16 - Prob. 45QAPCh. 16 - Calculate the pOH value corresponding to each of...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - Prob. 50QAPCh. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - Prob. 54QAPCh. 16 - 55. When 1 mole of gaseous hydrogen chloride is...Ch. 16 - . A bottle of acid solution is labeled “3 M HNO3.”...Ch. 16 - . Calculate the hydrogen ion concentration and the...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - . What characteristic properties do buffered...Ch. 16 - Prob. 60QAPCh. 16 - . Which component of a buffered solution is...Ch. 16 - Prob. 62QAPCh. 16 - . Which of the following combinations would act as...Ch. 16 - . A buffered solution is prepared containing...Ch. 16 - . The concepts of acid-base equilibria were...Ch. 16 - . Strong buses are bases that completely ionize in...Ch. 16 - Which of the following conditions indicate an...Ch. 16 - Which of the following conditions indicate a basic...Ch. 16 - Prob. 69APCh. 16 - Prob. 70APCh. 16 - Prob. 71APCh. 16 - Prob. 72APCh. 16 - Prob. 73APCh. 16 - Prob. 74APCh. 16 - 75. A conjugate acid-base pair Consists of two...Ch. 16 - . Acetate ion, C2H3O2- , has a stronger affinity...Ch. 16 - Prob. 77APCh. 16 - Prob. 78APCh. 16 - Prob. 79APCh. 16 - Prob. 80APCh. 16 - Prob. 81APCh. 16 - Prob. 82APCh. 16 - Prob. 83APCh. 16 - Prob. 84APCh. 16 - . A(n) _________ solution contains a conjugate...Ch. 16 - . When sodium hydroxide, NaOH, is added dropwise...Ch. 16 - . When hydrochloric acid, HCI. is added dropwise...Ch. 16 - . The following are representations of acid-base...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - Prob. 90APCh. 16 - . Write the conjugate base for each of the...Ch. 16 - Prob. 92APCh. 16 - Prob. 93APCh. 16 - . Calculate [H+] in each of the following...Ch. 16 - Prob. 95APCh. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 97APCh. 16 - Prob. 98APCh. 16 - Prob. 99APCh. 16 - . For each hydrogen or hydroxide ion concentration...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - Prob. 102APCh. 16 - Prob. 103APCh. 16 - Prob. 104APCh. 16 - . Write the formulas for three combinations of...Ch. 16 - . Choose pairs in which the species listed first...Ch. 16 - . Complete the table for each of the following...Ch. 16 - . Consider 0.25 M solutions of the following...
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- A buffer solution has a pH value of 9.8. Which value in the set of pH values 8.79.79.89.910.9 is the most likely value for the buffer solution pH after a. a small amount of strong acid has been added? b. a small amount of strong base has been added?arrow_forwardSulfanilic acid (NH2C6H4SO3H) is used in manufacturing dyes. It ionizes in water according to the equilibrium equation NH2C6H4SO3H(aq)+H2O(l)NH2C6H4SO3(aq)+H3O+(aq)Ka=5.9104 A buffer is prepared by dissolving 0.20 mol of sulfanilicacid and 0.13 mol of sodium sulfanilate (NaNH2C6H4SO3) in water and diluting to 1.00 L. Compute the pH of the solution. Suppose 0.040 mol of HCl is added to the buffer.Calculate the pH of the solution that results.arrow_forwardsWhat happens when an acid is added to a solution containing the HF/F buffer system?arrow_forward
- Use Le Chátelier's principle to explain what happens to the equilibrium H2O(l)H+(aq)+OH(aq) when a few drops of HCl are added to pure water.arrow_forward. Write the formulas for three combinations of weak acid and salt that would act as buffered solutions. For each of your combinations, write chemical equations showing how the components of the buffered solution would consume added acid and base.arrow_forwardTwo samples of 1.00 M HCl of equivalent volumes are prepared. One sample is titrated to the equivalence point with a 1.00 M solution of sodium hydroxide, while the other sample is titrated to the equivalence point with a 1.00 M solution of calcium hydroxide. a Compare the volumes of sodium hydroxide and calcium hydroxide required to reach the equivalence point for each titration. b Determine the pH of each solution halfway to the equivalence point. c Determine the pH of each solution at the equivalence point.arrow_forward
- A quantity of 0.25 M sodium hydroxide is added to a solution containing 0.15 mol of acetic acid. The final volume of the solution is 375 mL and the pH of this solution is 4.45. a What is the molar concentration of the sodium acetate? b How many milliliters of sodium hydroxide were added to the original solution? c What was the original concentration of the acetic acid?arrow_forwardA quantity of 0.15 M hydrochloric acid is added to a solution containing 0.10 mol of sodium acetate. Some of the sodium acetate is converted to acetic acid, resulting in a final volume of 650 mL of solution. The pH of the final solution is 4.56. a What is the molar concentration of the acetic acid? b How many milliliters of hydrochloric acid were added to the original solution? c What was the original concentration of the sodium acetate?arrow_forward7. Describe a buffered solution. Give three examples of buffered solutions. For each of your examples, write equations and explain how the components of the buffered solution consume added strong acids or bases. Why is buffering of solutions in biological systems so important?arrow_forward
- Another way to treat data from a pH titration is to graph the absolute value of the change in pH per change in milliliters added versus milliliters added (pH/mL versus mL added). Make this graph using your results from Exercise 61. What advantage might this method have over the traditional method for treating titration data?arrow_forward. Which component of a buffered solution is capable of combining with an added strong acid? Using your example from Exercise 60, show how this component would react with added HC1.arrow_forward. When sodium hydroxide, NaOH, is added dropwise to a buffered solution, the _______ component of the butter consumes the added hydroxide ion.arrow_forward
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