Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 16, Problem 86E
Interpretation Introduction
Interpretation:
The mass of
Concept Introduction: The
To determine: The mass of
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
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What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
▸ View Available Hint(s)
VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
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CH3
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1
-CH3
Chapter 16 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 16 - Prob. 16.1PCh. 16 - Prob. 16.1MPCh. 16 - Prob. 16.2PCh. 16 - Prob. 16.3PCh. 16 - Prob. 16.3MPCh. 16 - Prob. 16.4PCh. 16 - Prob. 16.4MPCh. 16 - Prob. 16.5PCh. 16 - Prob. 16.6PCh. 16 - Prob. 16.7P
Ch. 16 - For Practice 16.8 Calculate the molar solubility...Ch. 16 - Prob. 16.9PCh. 16 - Prob. 16.10PCh. 16 - For Practice 16.11
Which compound, FeCO3 or...Ch. 16 - Prob. 16.12PCh. 16 - For Practice 16.13
A 125.0-mL sample of solution...Ch. 16 - Prob. 1SAQCh. 16 - Prob. 2SAQCh. 16 - Prob. 3SAQCh. 16 - Prob. 4SAQCh. 16 - Prob. 5SAQCh. 16 - Prob. 6SAQCh. 16 - Prob. 7SAQCh. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQCh. 16 - Prob. 11SAQCh. 16 - Prob. 12SAQCh. 16 - Prob. 13SAQCh. 16 - Prob. 14SAQCh. 16 - Prob. 15SAQCh. 16 - Prob. 1ECh. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - 5. Calculate the percent ionization of a 0.15 M...Ch. 16 - 6. Calculate the percent ionization of a 0.13 M...Ch. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - 22. A 100.0-mL buffer solution is 0.175 M in HClO...Ch. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Which buffer system is the best choice to create a...Ch. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - A 20.0-mL sample of 0.125 M HNO3 titrated with...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Prob. 63ECh. 16 - Prob. 64ECh. 16 - Use the Kspvalue from Table 16.2 to calculate the...Ch. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Calculate the molar solubility of MX (Ksp= 1.27 ...Ch. 16 - Prob. 69ECh. 16 - Calculate the solubility (in grams per 1.00102mL...Ch. 16 - Prob. 71ECh. 16 - Determine if each compound is more soluble in...Ch. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - 76. Predict whether or not a precipitate forms...Ch. 16 - Prob. 77ECh. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Prob. 92ECh. 16 - One of the main components of hard water is CaCO3....Ch. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Calculate the solubility of silver chloride ii a...Ch. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - What relative masses of demethyl amine and...Ch. 16 - Prob. 102ECh. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Since soap and detergent action is hindered by...Ch. 16 - Prob. 106ECh. 16 - Prob. 107ECh. 16 - Determine the solubility of Cul in 0.40 M HCN...Ch. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - Prob. 113ECh. 16 - Prob. 114ECh. 16 - Prob. 115ECh. 16 - Prob. 116E
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- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
- 32S 16 Enter your answers numerically separated by a comma. Np. Nn = 跖 ΟΙ ΑΣΦ Submit Request Answer ? protons, neutronsarrow_forward2. Which dimethylcyclohexane compounds shown below exhibit symmetry and therefore are not chiral and would not rotate plane polarized light. 1 CH3 CH CH3 CH3 2 3 CH3arrow_forwardDon't used hand raitingarrow_forward
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