Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)
Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134649771
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 16, Problem 77P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

Amines are nitrogen-containing organic compounds.  They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.  Amines react with carbonyl compounds like ketone to form an imine or anenamine.  The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.  Amines also react with acyl chloride to form an amide.  The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group. Amines react with carbonyl compounds like ketone to form an imine or anenamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O. Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(c)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

Amines are nitrogen-containing organic compounds.  They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.  Amines react with carbonyl compounds like ketone to form an imine or anenamine.  The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.  Amines also react with acyl chloride to form an amide.  The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(d)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group. Amines react with carbonyl compounds like ketone to form an imine or anenamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O. Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Chapter 16 Solutions

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)

Ch. 16.4 - Show how the following compounds can be...Ch. 16.4 - Prob. 13PCh. 16.4 - Prob. 14PCh. 16.4 - In the mechanism for cyanohydrin formation, why is...Ch. 16.4 - Prob. 16PCh. 16.4 - Prob. 17PCh. 16.4 - Show two ways to convert an alkyl halide into a...Ch. 16.5 - Prob. 20PCh. 16.5 - Prob. 21PCh. 16.5 - Prob. 22PCh. 16.5 - Prob. 23PCh. 16.6 - Prob. 24PCh. 16.7 - What reducing agents should be used to obtain the...Ch. 16.7 - Prob. 26PCh. 16.8 - Prob. 27PCh. 16.8 - Prob. 28PCh. 16.8 - Prob. 29PCh. 16.8 - The pKa of protonated acetone is about 7.5. and...Ch. 16.8 - Prob. 31PCh. 16.8 - Prob. 32PCh. 16.8 - Prob. 33PCh. 16.8 - Excess ammonia must be used when a primary amine...Ch. 16.8 - The compounds commonly known as amino acids are...Ch. 16.9 - Hydration of an aldehyde is also catalyzed by...Ch. 16.9 - Which ketone forms the most hydrate in an aqueous...Ch. 16.9 - When trichloroacetaldehyde is dissolved in water,...Ch. 16.9 - Which of the following are a. hermiacetals? b....Ch. 16.9 - Prob. 40PCh. 16.9 - Explain why an acetal can be isolated but most...Ch. 16.10 - Prob. 42PCh. 16.10 - Prob. 43PCh. 16.10 - What products would be formed from the proceedings...Ch. 16.10 - a. In a six-step synthesis, what is the yield of...Ch. 16.10 - Show how each of the following compounds could be...Ch. 16.12 - Prob. 47PCh. 16.13 - Prob. 49PCh. 16.14 - Prob. 50PCh. 16.15 - Prob. 51PCh. 16.16 - Prob. 52PCh. 16 - Draw the structure for each of the following: a....Ch. 16 - Prob. 54PCh. 16 - Prob. 55PCh. 16 - Prob. 56PCh. 16 - a. Show the reagents required to form the primary...Ch. 16 - Prob. 58PCh. 16 - Prob. 59PCh. 16 - Using cyclohexanone as the starting material,...Ch. 16 - Propose a mechanism for each of the following...Ch. 16 - Show how each of the following compounds can be...Ch. 16 - Fill in the boxes:Ch. 16 - Prob. 64PCh. 16 - Identify A through O:Ch. 16 - Prob. 66PCh. 16 - Prob. 67PCh. 16 - Prob. 68PCh. 16 - How many signals would the product of the...Ch. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - Prob. 72PCh. 16 - Prob. 73PCh. 16 - Prob. 74PCh. 16 - Prob. 75PCh. 16 - Prob. 76PCh. 16 - Prob. 77PCh. 16 - Prob. 78PCh. 16 - Draw structure for A-D for each of the following:Ch. 16 - Prob. 80PCh. 16 - a. Propose a mechanism for the following reaction:...Ch. 16 - Prob. 82PCh. 16 - A compound gives the following IR spectrum. Upon...Ch. 16 - How can be following compounds be prepared from...Ch. 16 - Prob. 85PCh. 16 - Prob. 86PCh. 16 - Prob. 87PCh. 16 - In the presence of an acid catalyst, acetaldehyde...Ch. 16 - Prob. 89PCh. 16 - Prob. 90PCh. 16 - Prob. 91PCh. 16 - A compound reacts with methylmagnesium bromide...Ch. 16 - Show how each of the following compounds can be...Ch. 16 - Prob. 94PCh. 16 - The pKa values of the carboxylic acid groups of...Ch. 16 - The Baylis-Hillman reaction is a DABCO...Ch. 16 - Prob. 97PCh. 16 - Prob. 98P
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