EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Chapter 16, Problem 76E
A mixture of water and graphite is heated to 600 K. When the system comes to equilibrium, it contains 0.13 mol of H2, 0.13 mol of CO, 0.43 moI of H2O, and some graphite. Some O2 is added to the system, and a spark is applied so that the H2 reacts completely with the O2. Find the amount of CO in the flask when the system returns to equilibrium.
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
Х
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Draw TWO general chemical equation to prepare Symmetrical and non-Symmetrical ethers
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Chapter 16 Solutions
EBK CHEMISTRY
Ch. 16 - What is the correct expression for the equilibrium...Ch. 16 - Prob. 2SAQCh. 16 - Use the data below to find the equilibrium...Ch. 16 - The reaction shown here has a Kp = 4.5X102 AT 825...Ch. 16 - Consider the reaction between NO and Cl2 to form...Ch. 16 - Prob. 6SAQCh. 16 - Consider the reaction between iodine gas and...Ch. 16 - Prob. 8SAQCh. 16 - The decomposition of NH4HS is endothermic:...Ch. 16 - The solid XY decomposes into gaseous X and Y:...
Ch. 16 - What is the effect of adding helium gas (at...Ch. 16 - Prob. 12SAQCh. 16 - How does a developing fetus get oxygen in the...Ch. 16 - What is dynamic equilibrium? Why is it called...Ch. 16 - Give the general expression for the equilibrium...Ch. 16 - What is the significance of the equilibrium...Ch. 16 - What happens to the value of the equilibrium...Ch. 16 - If two reactions sum to an overall reaction, and...Ch. 16 - Explain the difference between Kcand Kp. For a...Ch. 16 - What units should you use when expressing...Ch. 16 - Why do we omit the concentrations of solids and...Ch. 16 - Does the value of the equilibrium constant depend...Ch. 16 - Explain how you might deduce the equilibrium...Ch. 16 - What is the definition of the reaction quotient ()...Ch. 16 - What is the value of when each reactant and...Ch. 16 - Prob. 14ECh. 16 - Many equilibrium calculations involve finding the...Ch. 16 - In equilibrium problems involving equilibrium...Ch. 16 - What happens to a chemical system at equilibrium...Ch. 16 - What is the effect of a change in concentration of...Ch. 16 - What is the effect of a change in volume on a...Ch. 16 - What is the effect of temperature change on a...Ch. 16 - Write an expression for the equilibrium constant...Ch. 16 - Find and fix each mistake in the equilibrium...Ch. 16 - When the reaction comes to equilibrium, will the...Ch. 16 - Ethene (C2H4) can be halogenated by this reaction:...Ch. 16 - H2 and I2 are combined in a flask and allowed to...Ch. 16 - A chemist trying to synthesize a particular...Ch. 16 - This reaction has an equilibrium constant of...Ch. 16 - This reaction has an equilibrium constant of...Ch. 16 - Prob. 29ECh. 16 - Use the following reactions and their equilibrium...Ch. 16 - Calculate Kc for reaction a. I2(g)2I(g)Kp=6.261022...Ch. 16 - Calculate Kpfor each reaction. a. N2O4(g)2NO2(g)...Ch. 16 - Write an equilibrium expression for each chemical...Ch. 16 - Find and fix the mistake in the equilibrium...Ch. 16 - Consider the reaction: CO(g)+2H2(g)CH3OH(g) An...Ch. 16 - Consider the reaction: NH4HS(s)NH3(g)+H2S(g) An...Ch. 16 - Consider the reaction: N2(g)+3H2(g)2NH3(g)...Ch. 16 - Consider the reaction: H2(g)+I2(g)2HI(g) Complete...Ch. 16 - Consider the reaction: 2NO(g)+Br2(g)2NOBr(g)Kp=...Ch. 16 - Consider the reaction:...Ch. 16 - For the reaction A(g)2B(g) , a reaction vessel...Ch. 16 - For the reaction 2A(g)B(g)+2C(g) , a reaction...Ch. 16 - Consider the reaction:...Ch. 16 - Consider the reaction: SO2Cl2(g)SO2+Cl2(g) A...Ch. 16 - Consider the reaction: H2(g)+I2(g)2HI(g) A...Ch. 16 - Consider the reaction. CO(g)+2H2(g)CH3OH(g) A...Ch. 16 - Consider the reaction: NH4HS(s)NH3(g)+H2S(g) At a...Ch. 16 - Consider the reaction:...Ch. 16 - Silver sulfate dissolves in water according to the...Ch. 16 - Nitrogen dioxide reacts with itself according to...Ch. 16 - Consider the reaction and the associated...Ch. 16 - Consider the reaction and the associated...Ch. 16 - For the reaction Kc= 0.513 at 500K. N2O4(g)2NO2(g)...Ch. 16 - For the reaction, Kc= 255 at 1000 K...Ch. 16 - Consider the reaction: NiO(s)+CO(g)Ni(s)+CO2(g)...Ch. 16 - Consider the reaction: CO(g)+H2O(g)CO2(g)+H2(g)Kc=...Ch. 16 - Consider the reaction: HC 2 H 3 O 2 (aq)+ H 2 O(l)...Ch. 16 - Prob. 58ECh. 16 - Consider the reaction:...Ch. 16 - Consider the reaction:...Ch. 16 - Consider the reaction: A(g)B(g)+C(g) Find the...Ch. 16 - Consider the reaction: A(g)2B(g) Find the...Ch. 16 - Consider this reaction at equilibrium:...Ch. 16 - Consider this reaction at equilibrium:...Ch. 16 - Consider this reaction at equilibrium:...Ch. 16 - Prob. 66ECh. 16 - Each reaction is allowed to come to equilibrium,...Ch. 16 - Prob. 68ECh. 16 - This reaction is endothermic: C(s)+CO2(g)2CO(g)...Ch. 16 - This reaction is exothermic:...Ch. 16 - Coal, which is primarily carbon, can be converted...Ch. 16 - Coal can be used to generate hydrogen gas (a...Ch. 16 - Carbon monoxide replaces oxygen in oxygenated...Ch. 16 - Nitrogen monoxide is a pollutant in the lower...Ch. 16 - The reaction CO2(g)+C(s)2CO(g) has Kp= 5.78 at...Ch. 16 - A mixture of water and graphite is heated to 600...Ch. 16 - At 650 K, the reaction MgCO3(s)MgO(s)+CO2(g) has...Ch. 16 - A system at equilibrium contains I2(g) at a...Ch. 16 - Consider the exothermic reaction:...Ch. 16 - Consider the endothermic reaction:...Ch. 16 - Consider the reaction: H2(g)+I2(g)2HI(g) A...Ch. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - The system described by the reaction:...Ch. 16 - A reaction vessel at 27017°C contains a mixture of...Ch. 16 - At 70 K, CCl4 decomposes to carbon and chlorine....Ch. 16 - The equilibrium constant for the reaction...Ch. 16 - A sample of CaCO3(s) is introduced into a sealed...Ch. 16 - An equilibrium mixture contains N2O4, (P = O.28)...Ch. 16 - Carbon monoxide and chlorine gas react to form...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Nitrogen monoxide reacts with chlorine gas...Ch. 16 - At a given temperature, a system containing O2(g)...Ch. 16 - A sample of pure NO2 is heated to 337 °C, at which...Ch. 16 - When N2O5(g) is heated, it dissociates into...Ch. 16 - A sample of SO3 is introduced into an evacuated...Ch. 16 - A reaction A(g)B(g) has an equilibrium constant of...Ch. 16 - The reaction A(g)2B(g) has an equilibrium constant...Ch. 16 - A particular reaction has an equilibrium constant...Ch. 16 - Consider the reaction: aA(g)bB(g) Each of the...Ch. 16 - Consider the simple one-step reaction: A(g)B(g)...
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- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. OCH 3 (Choose one) OH (Choose one) Br (Choose one) Explanation Check NO2 (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forward
- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forwardAssign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Brarrow_forwarddescrive the energy levels of an atom and howan electron moces between themarrow_forward
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