Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337671323
Author: ZUMDAHL
Publisher: Cengage
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Chapter 16, Problem 65AP
. The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3.
a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia.
b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.
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Determine whether the following reaction is an example of a nucleophilic substitution reaction:
H
NO2
H+
NO 2
+
Molecule A
Molecule B
Is this a nucleophilic substitution reaction?
If this is a nucleophilic substitution reaction, answer the remaining questions in this table.
What word or two-word phrase is used to describe the role Molecule A plays in this reaction?
What word or two-word phrase is used to describe the role Molecule B plays in this reaction?
Use a 6 + symbol to label the electrophilic carbon that is attacked during the substitution.
Highlight the leaving group on the appropriate reactant.
O Yes
○ No
☐
0
dx
000
HE
?
Draw the major organic product of the
Bronsted acid-base reaction.
Include all lone pairs and charges as
appropriate. Ignore any counterions.
:0:
NaOH
H
5. Calculate the total amount of heat transferred as 50 g of wat Specific heat H₂O (g) 2.00 J/g°C
-10 °C.
Specific heat H₂O (1)
Specific heat H₂O (s)
4.18 J/g°C
2.11 J/g°C
Heat of vaporization
2260 J/g
Heat of fusion
334 J/g
Melting point
0°C
6. Calculate the total amount of heat transferred as 25 g of
water is heated from 50 °C to 100 °C as a gas.
Boiling point
100 °C
Chapter 16 Solutions
Introductory Chemistry: A Foundation
Ch. 16.1 - Exercise 16.1 Which of the following represent...Ch. 16.2 - Vinegar contains acetic acid and is used in salad...Ch. 16.3 - Exercise 16.2 Calculate [H+] in a solution in...Ch. 16.4 - Prob. 16.3SCCh. 16.4 - Prob. 1CTCh. 16.4 - Prob. 16.4SCCh. 16.4 - Exercise 16.5 The pH of rainwater in a polluted...Ch. 16.4 - Exercise 16.6 The pOH of a liquid drain cleaner...Ch. 16.5 - Exercise 16.7 Calculate the pH of a solution of...Ch. 16 - You are asked for the H+ concentration in a...
Ch. 16 - Explain why Cl- does not affect the pH of an...Ch. 16 - Write the general reaction for an acid acting in...Ch. 16 - Differentiate among the terms concentrated,...Ch. 16 - What is meant by “pH”? True or false: A strong...Ch. 16 - Consider two separate solutions: one containing a...Ch. 16 - Prob. 7ALQCh. 16 - Prob. 8ALQCh. 16 - Stanley’s grade-point average (GPA) is 3.28. What...Ch. 16 - Prob. 10ALQCh. 16 - . Mixing together aqueous solutions of acetic acid...Ch. 16 - Prob. 12ALQCh. 16 - . Consider the equation:...Ch. 16 - . Choose the answer that best completes the...Ch. 16 - Prob. 15ALQCh. 16 - . The following figures are molecular-level...Ch. 16 - Prob. 17ALQCh. 16 - What are some physical properties that...Ch. 16 - Write an equation showing how HCl(g) behaves as an...Ch. 16 - Prob. 3QAPCh. 16 - How do the components of a conjugate acid—base...Ch. 16 - 5. Given the general equation illustrating the...Ch. 16 - According to Arrhenius, ____________ produce...Ch. 16 - Which of the following do not represent a...Ch. 16 - Which of the following do not represent a...Ch. 16 - In each of the following chemical equations,...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - Prob. 13QAPCh. 16 - . Write the conjugate base for each of the...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . What does it mean to say that an acid is strong...Ch. 16 - Prob. 18QAPCh. 16 - . How is the strength of an acid related to the...Ch. 16 - . A strong acid has a weak conjugate base, whereas...Ch. 16 - . Write the formula for the hydronium ion. Write...Ch. 16 - Prob. 22QAPCh. 16 - . Organic acids contain the carboxyl group Using...Ch. 16 - Prob. 24QAPCh. 16 - 25. Which of the following acids have relatively...Ch. 16 - . The “Chemistry in Focus” segment Plants Fight...Ch. 16 - . Water is the most common amphoteric substance,...Ch. 16 - . Anions containing hydrogen (for example. HCO3and...Ch. 16 - . What is meant by the iou-product constant for...Ch. 16 - . What happens to the hydroxide ion concentration...Ch. 16 - Prob. 31QAPCh. 16 - Prob. 32QAPCh. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - 35. For each pair of concentrations, tell which...Ch. 16 - . For each pair of concentrations, tell which...Ch. 16 - . Why do scientists tend to express the acidity of...Ch. 16 - . Using Fig. 16.3, list the approximate pH value...Ch. 16 - . For a hydrogen ion concentration of 2.33106M,...Ch. 16 - . The “Chemistry in Focus” segment Garden-Variety...Ch. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 42QAPCh. 16 - Prob. 43QAPCh. 16 - Prob. 44QAPCh. 16 - Prob. 45QAPCh. 16 - . Calculate the pOH value corresponding to each of...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - Prob. 54QAPCh. 16 - 55. When 1 mole of gaseous hydrogen chloride is...Ch. 16 - . A bottle of acid solution is labeled “3 M HNO3.”...Ch. 16 - . Calculate the hydrogen ion concentration and the...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - . What characteristic properties do buffered...Ch. 16 - Prob. 60QAPCh. 16 - . Which component of a buffered solution is...Ch. 16 - Prob. 62QAPCh. 16 - . Which of the following combinations would act as...Ch. 16 - . A buffered solution is prepared containing...Ch. 16 - . The concepts of acid-base equilibria were...Ch. 16 - . Strong buses are bases that completely ionize in...Ch. 16 - Prob. 67APCh. 16 - Prob. 68APCh. 16 - Prob. 69APCh. 16 - Prob. 70APCh. 16 - Prob. 71APCh. 16 - Prob. 72APCh. 16 - Prob. 73APCh. 16 - Prob. 74APCh. 16 - 75. A conjugate acid-base pair Consists of two...Ch. 16 - . Acetate ion, C2H3O2- , has a stronger affinity...Ch. 16 - Prob. 77APCh. 16 - Prob. 78APCh. 16 - Prob. 79APCh. 16 - Prob. 80APCh. 16 - Prob. 81APCh. 16 - Prob. 82APCh. 16 - Prob. 83APCh. 16 - Prob. 84APCh. 16 - . A(n) _________ solution contains a conjugate...Ch. 16 - . When sodium hydroxide, NaOH, is added dropwise...Ch. 16 - . When hydrochloric acid, HCI. is added dropwise...Ch. 16 - . The following are representations of acid-base...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - Prob. 90APCh. 16 - . Write the conjugate base for each of the...Ch. 16 - . Of the following combinations, which would act...Ch. 16 - Prob. 93APCh. 16 - . Calculate [H+] in each of the following...Ch. 16 - Prob. 95APCh. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 97APCh. 16 - Prob. 98APCh. 16 - Prob. 99APCh. 16 - . For each hydrogen or hydroxide ion concentration...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - Prob. 102APCh. 16 - Prob. 103APCh. 16 - Prob. 104APCh. 16 - . Write the formulas for three combinations of...Ch. 16 - . Choose pairs in which the species listed first...Ch. 16 - . Complete the table for each of the following...Ch. 16 - . Consider 0.25 M solutions of the following...
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