Introductory Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (6th Edition) (New Chemistry Titles from Niva Tro)
6th Edition
ISBN: 9780134290812
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 16, Problem 5E
Interpretation Introduction
Interpretation: The blank space is to be filled in the given statement:
‘Good oxidising agents have a strong tendency to
Concept Introduction: Redox
During tredox reaction, one element undergoes oxidation reaction and the other one undergoes reduction reaction.
Oxidizing agent itself gets reduced by accepting the electrons from other substance and thus, causes oxidation of the other substance.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 16 Solutions
Introductory Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (6th Edition) (New Chemistry Titles from Niva Tro)
Ch. 16 - Q1. Which substance is being oxidized in the...Ch. 16 - What always happens to an oxidizing agent during a...Ch. 16 - Q3. What is the oxidation state of carbon in...Ch. 16 - Q4. In which compound does phosphorus have the...Ch. 16 - Sodium reacts with water according to the...Ch. 16 - Q6. How many electrons are exchanged when this...Ch. 16 - Prob. 7SAQCh. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQ
Ch. 16 - 1. What is a fuel-cell electric vehicle?
Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - 20. Any half-reaction in the activity series will...Ch. 16 - How can you use the activity series to determine...Ch. 16 - What is electrical current? Explain how a simple...Ch. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 38. For each of the reactions in Problem 36,...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - 45. Assign an oxidation state to each element or...Ch. 16 - Prob. 46ECh. 16 - 47. Assign an oxidation state to each atom in each...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Assign an oxidation state to each element in each...Ch. 16 - 59. Use oxidation states to identify the oxidizing...Ch. 16 - Prob. 60ECh. 16 - 61. Balance each redox reaction using the...Ch. 16 - Prob. 62ECh. 16 - Classify each half-reaction occurring in acidic...Ch. 16 - 64. Classify each half-reaction occurring in...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Balance each redox reaction occurring in basic...Ch. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - 77. Determine whether each redox occurs...Ch. 16 - Prob. 78ECh. 16 - 79. Suppose you wanted to cause ions to come out...Ch. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - 82. Which metal in the activity series is oxidized...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - 86. Make a sketch of an electrochemical cell with...Ch. 16 - Prob. 87ECh. 16 - The following reaction occurs at the cathode of an...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Make a sketch of an electrolysis cell that could...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - 95. Determine whether each reaction is a redox...Ch. 16 - Prob. 96ECh. 16 - Consider the unbalanced redox reaction....Ch. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - 102. A 1.012-mL sample of a salt containing is...Ch. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Determine whether HI can dissolve each metal...Ch. 16 - 106. Determine whether HI can dissolve each metal...Ch. 16 - Prob. 107ECh. 16 - 108. One graduated cylinder containing 1.00 mL of...Ch. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - 113. Consider the molecular view of an...Ch. 16 - Which of your group’s cells do you think would...Ch. 16 - Data Interpretation and Analysis
116. We can use...
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