ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
Question
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Chapter 16, Problem 59P

a.

Interpretation Introduction

Interpretation:

Name the given compound.

Concept introduction:

The nomenclature of aldehydes and ketones. The functional group in the aldehydes and Ketones are carbonyl group.

Naming Aldehydes:

Aldehydes have at least one hydrogen attached to the carbonyl carbon atom.

The IUPAC naming of an aldehydes is obtained by replacing the final "e" on the name of the parent hydrocarbon with "al".

The common name of the aldehyde is substituted for "oic acid" at the end of parent hydrocarbon chain.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  1

Naming Ketones:

Carbonyl carbon atom attached to the two oxygen atoms.

The IUPAC name of a ketones are obtained by replacing the "e" on the end of the parent hydrocarbon with "one".

Only few ketones have common name.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  2

b.

Interpretation Introduction

Interpretation:

Name the given compound.

Concept introduction:

Naming Aldehydes:

Aldehydes have at least one hydrogen attached to the carbonyl carbon atom.

The IUPAC naming of an aldehydes is obtained by replacing the final "e" on the name of the parent hydrocarbon with "al".

The common name of the aldehyde is substituted for "oic acid" at the end of parent hydrocarbon chain.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  3

Naming Ketones:

Carbonyl carbon atom attached to the two oxygen atoms.

The IUPAC name of a ketones are obtained by replacing the "e" on the end of the parent hydrocarbon with "one".

Only few ketones have common name.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  4

c.

Interpretation Introduction

Interpretation:

Name the given compound.

Concept introduction:

Naming Aldehydes:

Aldehydes have at least one hydrogen attached to the carbonyl carbon atom.

The IUPAC naming of an aldehydes is obtained by replacing the final "e" on the name of the parent hydrocarbon with "al".

The common name of the aldehyde is substituted for "oic acid" at the end of parent hydrocarbon chain.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  5

Naming Ketones:

Carbonyl carbon atom attached to the two oxygen atoms.

The IUPAC name of a ketones are obtained by replacing the "e" on the end of the parent hydrocarbon with "one".

Only few ketones have common name.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  6

d.

Interpretation Introduction

Interpretation:

Name the given compound.

Concept introduction:

Naming Aldehydes:

Aldehydes have at least one hydrogen attached to the carbonyl carbon atom.

The IUPAC naming of an aldehydes is obtained by replacing the final "e" on the name of the parent hydrocarbon with "al".

The common name of the aldehyde is substituted for "oic acid" at the end of parent hydrocarbon chain.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  7

Naming Ketones:

Carbonyl carbon atom attached to the two oxygen atoms.

The IUPAC name of a ketones are obtained by replacing the "e" on the end of the parent hydrocarbon with "one".

Only few ketones have common name.

For example:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 16, Problem 59P , additional homework tip  8

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Chapter 16 Solutions

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL

Ch. 16.4 - Show how the following compounds can be...Ch. 16.4 - Prob. 13PCh. 16.4 - Prob. 14PCh. 16.4 - In the mechanism for cyanohydrin formation, why is...Ch. 16.4 - Prob. 16PCh. 16.4 - Prob. 17PCh. 16.4 - Show two ways to convert an alkyl halide into a...Ch. 16.5 - Prob. 20PCh. 16.5 - Prob. 21PCh. 16.5 - Prob. 22PCh. 16.5 - Prob. 23PCh. 16.6 - Prob. 24PCh. 16.7 - What reducing agents should be used to obtain the...Ch. 16.7 - Prob. 26PCh. 16.8 - Prob. 27PCh. 16.8 - Prob. 28PCh. 16.8 - Prob. 29PCh. 16.8 - The pKa of protonated acetone is about 7.5. and...Ch. 16.8 - Prob. 31PCh. 16.8 - Prob. 32PCh. 16.8 - Prob. 33PCh. 16.8 - Excess ammonia must be used when a primary amine...Ch. 16.8 - The compounds commonly known as amino acids are...Ch. 16.9 - Hydration of an aldehyde is also catalyzed by...Ch. 16.9 - Which ketone forms the most hydrate in an aqueous...Ch. 16.9 - When trichloroacetaldehyde is dissolved in water,...Ch. 16.9 - Which of the following are a. hermiacetals? b....Ch. 16.9 - Prob. 40PCh. 16.9 - Explain why an acetal can be isolated but most...Ch. 16.10 - Prob. 42PCh. 16.10 - Prob. 43PCh. 16.10 - What products would be formed from the proceedings...Ch. 16.10 - a. In a six-step synthesis, what is the yield of...Ch. 16.10 - Show how each of the following compounds could be...Ch. 16.12 - Prob. 47PCh. 16.13 - Prob. 49PCh. 16.14 - Prob. 50PCh. 16.15 - Prob. 51PCh. 16.16 - Prob. 52PCh. 16 - Draw the structure for each of the following: a....Ch. 16 - Prob. 54PCh. 16 - Prob. 55PCh. 16 - Prob. 56PCh. 16 - a. Show the reagents required to form the primary...Ch. 16 - Prob. 58PCh. 16 - Prob. 59PCh. 16 - Using cyclohexanone as the starting material,...Ch. 16 - Propose a mechanism for each of the following...Ch. 16 - Show how each of the following compounds can be...Ch. 16 - Fill in the boxes:Ch. 16 - Prob. 64PCh. 16 - Identify A through O:Ch. 16 - Prob. 66PCh. 16 - Prob. 67PCh. 16 - Prob. 68PCh. 16 - How many signals would the product of the...Ch. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - Prob. 72PCh. 16 - Prob. 73PCh. 16 - Prob. 74PCh. 16 - Prob. 75PCh. 16 - Prob. 76PCh. 16 - Prob. 77PCh. 16 - Prob. 78PCh. 16 - Draw structure for A-D for each of the following:Ch. 16 - Prob. 80PCh. 16 - a. Propose a mechanism for the following reaction:...Ch. 16 - Prob. 82PCh. 16 - A compound gives the following IR spectrum. Upon...Ch. 16 - How can be following compounds be prepared from...Ch. 16 - Prob. 85PCh. 16 - Prob. 86PCh. 16 - Prob. 87PCh. 16 - In the presence of an acid catalyst, acetaldehyde...Ch. 16 - Prob. 89PCh. 16 - Prob. 90PCh. 16 - Prob. 91PCh. 16 - A compound reacts with methylmagnesium bromide...Ch. 16 - Show how each of the following compounds can be...Ch. 16 - Prob. 94PCh. 16 - The pKa values of the carboxylic acid groups of...Ch. 16 - The Baylis-Hillman reaction is a DABCO...Ch. 16 - Prob. 97PCh. 16 - Prob. 98P
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