EBK INTRODUCTORY CHEMISTRY
EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 9780134553153
Author: CORWIN
Publisher: PEARSON CO
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Chapter 16, Problem 32E
Interpretation Introduction

(a)

Interpretation:

The direction of the equilibrium on decreasing concentration of HNO2 is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(b)

Interpretation:

The effect of decreasing concentration of hydrogen ion is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(c)

Interpretation:

The direction of the equilibrium on increasing concentration of HNO2 is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(d)

Interpretation:

The direction of the equilibrium on increasing concentration of NO2 is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(e)

Interpretation:

The direction of the equilibrium on adding solid KNO2 is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(f)

Interpretation:

The direction of the equilibrium on adding solid KCl is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(g)

Interpretation:

The direction of the equilibrium on adding solid KOH is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

Interpretation Introduction

(h)

Interpretation:

The direction of the equilibrium on increasing pH is to be stated.

Concept introduction:

Equilibrium is the state where the concentration of the reactant is equal to the concentration of the product. According to Le Chatelier’s Principle, it states that the equilibrium shifts in such a way or a direction that it can reduce the effect of change.

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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why

Chapter 16 Solutions

EBK INTRODUCTORY CHEMISTRY

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