Chemistry In Focus
7th Edition
ISBN: 9781337670425
Author: Tro
Publisher: Cengage
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Chapter 16, Problem 31E
Draw a schematic diagram of DNA. Show the double-helix structure, the molecular backbone, and the complementary nature of the base pairs.
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Please predict the products for each of the
following reactions.
Clearly show the regiochemistry (Markovnikov
vs anti-Markovnikov) and stereochemistry
(syn- vs anti- or both).
If a mixture of enantiomers is formed, please
draw all the enantiomers.
Hint: In this case you must choose the best
answer to demonstrate the stereochemistry of
H2 addition.
1.03
2. (CH3)2S
BIZ
CH₂OH
2. DMS
KMnO4, NaOH
ΖΗ
Pd or Pt (catalyst)
HBr
20 1
HBr
ROOR (peroxide)
HO
H-SO
HC
12 11 10
BH, THE
2. H2O2, NaOH
Brz
cold
HI
19
18
17
16
MCPBA
15
14
13
A
Br
H₂O
BH3⚫THF
Brz
EtOH
Pd or Ni (catalyst)
D₂ (deuterium)
1. Os04
2. H2O2
CH3CO3H
(peroxyacid)
1. MCPBA
2. H₂O*
H
B
+
H
H
H
"H
C
H
H
D
Explain how Beer’s Law can be used to determine the concentration in a selected food sample. Provide examples.
Explain the importance of having a sampling plan with respect to food analysis.
Explain the importance of having a sampling plan with respect to food analysis. Provide examples.
Chapter 16 Solutions
Chemistry In Focus
Ch. 16 - Prob. 1SCCh. 16 - Prob. 2SCCh. 16 - Prob. 3SCCh. 16 - Prob. 4SCCh. 16 - Prob. 16.1YTCh. 16 - Saturated and Unsaturated Fats Which of the...Ch. 16 - Prob. 16.3YTCh. 16 - Prob. 16.4YTCh. 16 - Identifying Amino Acids Which of the following...Ch. 16 - Drawing Peptide Structures Draw the tripeptide...
Ch. 16 - DNA Complementarity Draw the complementary strand...Ch. 16 - List the four major classes of biochemical...Ch. 16 - Why are fats more efficient than carbohydrates for...Ch. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Why do carbohydrates contain less energy per gram...Ch. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - What is the difference between DNA and RNA?Ch. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - What are chromosomes? How many exist in humans?Ch. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Draw a schematic diagram of DNA. Show the...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Explain how recombinant DNA technology has made...Ch. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - How can genetic engineering be used to treat...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - What are the dangers inherent in applying genetic...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Which molecule is an amino acid?Ch. 16 - Which molecule is an amino acid?Ch. 16 - Prob. 57ECh. 16 - Classify each molecule as a lipid, carbohydrate,...Ch. 16 - Prob. 59ECh. 16 - Draw the structure for the dipeptide Ala-Gly. How...Ch. 16 - Draw the structure for the tripeptide Leu-Leu-Leu....Ch. 16 - Draw the structure for the tripeptide Ser-Ser-Ser....Ch. 16 - Prob. 63ECh. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73E
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- Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. cold KMnO4, NaOH 2. DMS 1. 03 CH3OH Br2 1. 03 2. (CH3)2S H₂ Pd or Pt (catalyst) HBr 18 19 20 1 HBr ROOR (peroxide) H₂O H₂SO4 HCI HI 17 16 6 15 MCPBA 1. BH3 THF 2. H₂O2, NaOH 1. OsO4 2. H₂O₂ 110 CH3CO₂H (peroxyacid) 1. MCPBA 2. H₂O* Br2 H₂O BH3 THF B12 EtOH Pd or Ni (catalyst) D₂ (deuterium) Bra A B C D H OH H OH OH H OH α α α OH H OH OH фон d H "Harrow_forwardBriefly indicate the models that describe the structure of the interface: Helmholtz-Perrin, Gouy-Chapman, Stern and Grahame models.arrow_forwardElectrochemistry. Briefly describe the Gibbs model and the Gibbs absorption equation.arrow_forward
- Briefly state the electrocapillary equation for ideally polarized electrodes.arrow_forwardWhat is surface excess according to the Gibbs model?arrow_forwardUsing Benzene as starting materid show how each of the Following molecules Contel Ve syntheswed CHI 9. b -50311 с CHY 503H Ночто d. อ •NOV e 11-0-650 NO2arrow_forward
- The molecule PYRIDINE, 6th electrons and is therefore aromatre and is Assigned the Following structure contering Since aromatk moleculoy undergo electrophilic anomatic substitution, Pyridine shodd undergo The Following reaction + HNO3 12504 a. write all of the possible Mononitration Products that could Result From this reaction 18. Bared upon the reaction mechanison determime which of these producty would be the major Product of the hegetionarrow_forwarda. Explain Why electron withdrawing groups tend to be meta-Directors. Your answer Should lyclude all apropriate. Resonance contributing Structures fo. Explain why -ll is an outho -tura drccton even though chlorine has a very High Electronegativityarrow_forward9. Write Me product as well as the reaction Mechanism For each of the Following Vanctions +H₂504 4.50+ T C. +212 Fellz 237 b. Praw the potential energy Diagrams For each OF Mese Rauctions and account For any differences that appear in the two potential Puergy Diagrams which of here two reactions 19 Found to be Reversable, Rationalice your answer based upon the venation mechanisms and the potential energy diagrams.arrow_forward
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