Pearson eText -- Introductory Chemistry -- Instant Access (Pearson+)
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Chapter 16, Problem 30E
Interpretation Introduction
Interpretation:
The process of
Concept Introduction:
The
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22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
trophilic aromatic substitution that shows the role of each group in stabilizing the
intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
Show how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.
Help me solve this problem. Thank you in advance.
Chapter 16 Solutions
Pearson eText -- Introductory Chemistry -- Instant Access (Pearson+)
Ch. 16 - Q1. Which substance is being oxidized in the...Ch. 16 - What always happens to an oxidizing agent during a...Ch. 16 - Q3. What is the oxidation state of carbon in...Ch. 16 - Q4. In which compound does phosphorus have the...Ch. 16 - Sodium reacts with water according to the...Ch. 16 - Q6. How many electrons are exchanged when this...Ch. 16 - Prob. 7SAQCh. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQ
Ch. 16 - 1. What is a fuel-cell electric vehicle?
Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - 20. Any half-reaction in the activity series will...Ch. 16 - How can you use the activity series to determine...Ch. 16 - What is electrical current? Explain how a simple...Ch. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 38. For each of the reactions in Problem 36,...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - 45. Assign an oxidation state to each element or...Ch. 16 - Prob. 46ECh. 16 - 47. Assign an oxidation state to each atom in each...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Assign an oxidation state to each element in each...Ch. 16 - 59. Use oxidation states to identify the oxidizing...Ch. 16 - Prob. 60ECh. 16 - 61. Balance each redox reaction using the...Ch. 16 - Prob. 62ECh. 16 - Classify each half-reaction occurring in acidic...Ch. 16 - 64. Classify each half-reaction occurring in...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Balance each redox reaction occurring in basic...Ch. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - 77. Determine whether each redox occurs...Ch. 16 - Prob. 78ECh. 16 - 79. Suppose you wanted to cause ions to come out...Ch. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - 82. Which metal in the activity series is oxidized...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - 86. Make a sketch of an electrochemical cell with...Ch. 16 - Prob. 87ECh. 16 - The following reaction occurs at the cathode of an...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Make a sketch of an electrolysis cell that could...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - 95. Determine whether each reaction is a redox...Ch. 16 - Prob. 96ECh. 16 - Consider the unbalanced redox reaction....Ch. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - 102. A 1.012-mL sample of a salt containing is...Ch. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Determine whether HI can dissolve each metal...Ch. 16 - 106. Determine whether HI can dissolve each metal...Ch. 16 - Prob. 107ECh. 16 - 108. One graduated cylinder containing 1.00 mL of...Ch. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - 113. Consider the molecular view of an...Ch. 16 - Which of your group’s cells do you think would...Ch. 16 - Data Interpretation and Analysis
116. We can use...
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- 22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁arrow_forwardIs an acid-base reaction the only type of reaction that would cause leavening products to rise?arrow_forwardHelp me understand this! Thank you in advance.arrow_forward
- 22.22 For each compound, indicate which group on the ring is more strongly activating and then draw a structural formula of the major product formed by nitration of the compound. Br CHO (a) CH3 (b) (c) CHO CH3 SO₂H (d) ☑ OCHS NO₂ (e) (f) CO₂H NHCOCH3 NHCOCH, (h) CHS 22.23 The following molecules each contain two aromatic rings. (b) 000-100- H3C (a) (c) Which ring in each undergoes electrophilic aromatic substitution more readily? Draw the major product formed on nitration.arrow_forwardV Consider this step in a radical reaction: Br: ? What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. ⚫ionization termination initialization neutralization none of the abc Explanation Check 80 Ο F3 F1 F2 2 F4 01 % do5 $ 94 #3 X 5 C MacBook Air 25 F5 F6 66 ©2025 ˇ F7 29 & 7 8arrow_forwardShow how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.arrow_forward
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