Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 1.6, Problem 2CP
Convert
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Reaction Fill-ins Part 2! Predict the
product(s) OR starting material of the
following reactions. Remember,
Hydride shifts are possible if/when a
more stable carbocation can exist
(depending on reaction mechanism)!
Put your answers in the indicated
boxes d.
d.
ง
HCI
A cylinder contains 12 L of water vapour at 150˚C and 5 atm. The temperature of the water vapour is raised to 175˚C, and the volume of the cylinder is reduced to 8.5 L. What is the final pressure of the gas in atmospheres?
assume that the gas is ideal
On the next page is an LC separation of the parabens found in baby wash. Parabens are
suspected in a link to breast cancer therefore an accurate way to quantitate them is desired.
a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for
all the terms in your calculation.
b. Is this a "good" value for a capacity factor? Explain.
c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly
what values you used in your calculation.
MAU
| Methyl paraben
40
20
0
-2
Ethyl paraben n-Propyl paraben
n-Butyl paraben
App ID 22925
6
8
min
Chapter 1 Solutions
Chemistry
Ch. 1.1 - Practice Problem ATTEMPT
Express the freezing...Ch. 1.1 - Practice ProblemBUILD According to the website of...Ch. 1.1 - Prob. 1PPCCh. 1.2 - Prob. 1PPACh. 1.2 - Practice ProblemBUILD In Ray Bradbury's 1953 novel...Ch. 1.2 - Practice ProblemCONCEPTUALIZE If a single degree...Ch. 1.3 - Practice ProblemAttempt Given that 25 .0 mL of...Ch. 1.3 - Practice Problem BUILD
Calculate (a) the density...Ch. 1.3 - Practice ProblemCONCEPTUALIZE Using the picture of...Ch. 1.3 - The coldest temperature ever recorded on Earth was...
Ch. 1.3 - What is the density of an object that has a volume...Ch. 1.3 - A sample of water is heated from room temperature...Ch. 1.3 - Prob. 4CPCh. 1.4 - Prob. 1PPACh. 1.4 - Prob. 1PPBCh. 1.4 - Practice Problem CONCEPTUALIZE
The diagram on the...Ch. 1.4 - Prob. 1CPCh. 1.4 - Prob. 2CPCh. 1.5 - Practice Problem ATTEMPT
Determine the number of...Ch. 1.5 - Prob. 1PPBCh. 1.5 - Prob. 1PPCCh. 1.5 - 1.5.1 What volume of water does the graduated...Ch. 1.5 - Which of the following is the sum of the following...Ch. 1.5 - The true dependence of y on x is represented by...Ch. 1.5 - What is the result of the following calculation to...Ch. 1.6 - Practice ProblemATTEMPT Perform the following...Ch. 1.6 - Practice ProblemBUILD Perform the following...Ch. 1.6 - Practice Problem CONCEPTUALIZE
A citrus dealer in...Ch. 1.6 - The density of lithium metal is 535 kg/m 3 . What...Ch. 1.6 - 1.6.2 Convert to liters.
Ch. 1.6 - 1.6.3 What is the volume of a 5.75-g object that...Ch. 1.6 - How many cubic centimeters are there in a cubic...Ch. 1.7 - Practice Problem ATTEMPT
An empty container with...Ch. 1.7 - Practice Problem BUILD
Another empty container...Ch. 1.7 - Practice ProblemCONCEPTUALIZE Several pieces of...Ch. 1.8 - Practice ProblemATTEMPT The American Heart...Ch. 1.8 - Practice ProblemBUILD An object has a mass of...Ch. 1.8 - Practice ProblemCONCEPTUALIZE The diagram contains...Ch. 1.9 - Practice ProblemATTEMPT The density of silver is...Ch. 1.9 - Practice ProblemBUILD The density of mercury is 13...Ch. 1.9 - Practice ProblemCONCEPTUALIZE Each diagram [ ( i )...Ch. 1 - 1.1
Given that the density of gold is , calculate...Ch. 1 - Prob. 2KSPCh. 1 - Determine the density of the following object in...Ch. 1 - A 28-kg child can consume a maximum of 23...Ch. 1 - Define the terms chemistry and matter.Ch. 1 - 1.2 Explain what is meant by the scientific...Ch. 1 - what is the difference between a hypothesis and a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Identify the elements present in the following...Ch. 1 - Identify the elements present in the following...Ch. 1 - Give an example for each of the following terms:...Ch. 1 - 1.9 Give an example of a homogeneous mixture and...Ch. 1 - Give an example of an element and a compound. How...Ch. 1 - What is the number of known elements?Ch. 1 - Give the names of the elements represented by the...Ch. 1 - 1.13 Give the chemical symbols for the following...Ch. 1 - Classify each of the following substances as an...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Identify each of the diagrams shown here as a...Ch. 1 - Identify each of the diagrams shown here as an...Ch. 1 - Name the SI base units that are important in...Ch. 1 - 1.19 Write the numbers represented by the...Ch. 1 - 1.20 What units do chemists normally use for the...Ch. 1 - 1.21 What is the difference between mass and...Ch. 1 - 1.22 Describe the three temperature scales used in...Ch. 1 - Bromine is a reddish-brown liquid. Calculate its...Ch. 1 - Prob. 24QPCh. 1 - Prob. 25QPCh. 1 - Prob. 26QPCh. 1 - Prob. 27QPCh. 1 - The density of platinum (Pt) is 21 .5 g/cm 3 at...Ch. 1 - Convert the following temperatures to kelvin: (a)...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - What is the difference between qualitative data...Ch. 1 - Using examples, explain the difference between a...Ch. 1 - How does an intensive property differ from an...Ch. 1 - Determine which of the following properties are...Ch. 1 - Classify the following as qualitative or...Ch. 1 - 1.38 Determine whether the following statements...Ch. 1 - Determine whether each of the following describes...Ch. 1 - 1.40 A student pours 44.3 g of water at into a...Ch. 1 - Prob. 39QPCh. 1 - Comment on whether each of the following...Ch. 1 - What is the advantage of using scientific notation...Ch. 1 - Define significant figure. Discuss the importance...Ch. 1 - Distinguish between the terms accuracy and...Ch. 1 - 1.46 Express the following numbers in scientific...Ch. 1 - Express the following as decimals: (a) 1.52 × 10 −...Ch. 1 - Express the answers to the following calculations...Ch. 1 - 1.49 Express the answers to the following...Ch. 1 - 1.50 Determine the number of significant figures...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 50QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Three students ( A, B, and C ) are asked to...Ch. 1 - Three apprentice tailors ( X, Y, and Z ) are...Ch. 1 - Carry out the following conversions: (a) 22.6 m to...Ch. 1 - Carry out the following conversions: (a) 242 lb to...Ch. 1 - The average speed of helium at 25°C is 1255 m/s ....Ch. 1 - Prob. 57QPCh. 1 - Prob. 58QPCh. 1 - Prob. 59QPCh. 1 - 1.62 A 6.0-ft person weighs 168 lb. Express this...Ch. 1 - Prob. 61QPCh. 1 - For a fighter jet to take off from the deck of an...Ch. 1 - Prob. 63QPCh. 1 - Prob. 64QPCh. 1 - Carry out the following conversions: (a) 185 nm to...Ch. 1 - 1.68 Aluminum is a lightweight metal used in...Ch. 1 - Prob. 67QPCh. 1 - (a) Carbon monoxide ( CO ) is a poisonous gas...Ch. 1 - Prob. 69QPCh. 1 - A human brain weighs about 1 kg and contains about...Ch. 1 - Using the appropriate number of significant...Ch. 1 - 1.74 A piece of metal with a mass of 13.2 g was...Ch. 1 - 1.75 Which of the following statements describe...Ch. 1 - 1.76 In determining the density of a rectangular...Ch. 1 - Calculate the mass of each of the following: (a) a...Ch. 1 - 1.78 A cylindrical glass tube 12.7 cm in length is...Ch. 1 - The following procedure was used to determine the...Ch. 1 - 1.80 The speed of sound in air at room temperature...Ch. 1 - A piece of silver ( Ag ) metal weighing 194.3 g is...Ch. 1 - The experiment described in Problem 1.81 is a...Ch. 1 - A lead sphere has a mass of 1 .20 × 10 4 g . and...Ch. 1 - Lithium is the least dense metal known ( density =...Ch. 1 - At what temperature does the numerical reading on...Ch. 1 - Prob. 84APCh. 1 - Prob. 85APCh. 1 - A sheet of aluminum ( A1 ) foil hat a total area...Ch. 1 - Prob. 87APCh. 1 - 1.90 The surface area and average depth of the...Ch. 1 - The unit "troy ounce" is often used for precious...Ch. 1 - Prob. 90APCh. 1 - Calculate the percent error for the following...Ch. 1 - In water conservation, chemists spread a thin film...Ch. 1 - 1.95 You are given a liquid. Briefly describe the...Ch. 1 - A gas company in Massachusetts charges $1 .30 for...Ch. 1 - Prob. 95APCh. 1 - 1.98 A bank teller is asked to assemble sets of...Ch. 1 - Prob. 97APCh. 1 - 1.100 Venus, the second closest planet to the sun....Ch. 1 - Comment on whether each of the following is a...Ch. 1 - It has been estimated that 8.0 × 10 4 tons of gold...Ch. 1 - Prob. 101APCh. 1 - 1.104 Measurements show that 1.0 g of iron ...Ch. 1 - 1.105 The thin outer layer of Earth, called the...Ch. 1 - 1.106 The radius of a copper atom is roughly ....Ch. 1 - A graduated cylinder is filled to the 40.00-mL...Ch. 1 - A chemist mixes two liquids A and B to form a...Ch. 1 - A chemist in the nineteenth century prepared an...Ch. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - Prob. 109APCh. 1 - Prob. 110APCh. 1 - Chalcopyrite, the principal one of copper ( Cu ) ,...Ch. 1 - 1.114 Vanillin (used to flavor vanilla ice cream...Ch. 1 - One gallon of gasoline in an automobile’s engine...Ch. 1 - 1.116 Magnesium (Mg) is a valuable metal used in...Ch. 1 - Prob. 115APCh. 1 - The natural abundances of elements in the human...Ch. 1 - A resting adult requires about 240 mL of pure...Ch. 1 - 1.120 (a) Referring to Problem 1.119. calculate...Ch. 1 - The medicinal thermometer commonly used in homes...Ch. 1 - TUMS is a popular remedy for acid indigestion. A...Ch. 1 - Prob. 121APCh. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- d. In Figure 4, each stationary phase shows some negative correlation between plate count and retention factor. In other words, as k' increases, N decreases. Explain this relationship between k' and N. Plate Count (N) 4000 3500 2500 2000 1500 1000 Figure 4. Column efficiency (N) vs retention factor (k') for 22 nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000 Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain k' less than 15, which was achieved for most solutes as follows: FMS (30/70 A/W), PGC (60/40), COZ (80/20). Slightly different compositions were used for the most highly retained solutes. All columns were 50 mm × 4.6 mm id and packed with 5 um particles, except for COZ, which was packed with 3 um particles. All other chromatographic conditions were constant: column length 5 cm, column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C, and injection volume 0.5 μL Log(k'x/K'ethylbenzene) FMS 1.5 1.0 0.5 0.0 ཐྭ ཋ ཤྩ བྷྲ ; 500 0 5 10…arrow_forwardf. Predict how the van Deemter curve in Figure 7 would change if the temperature were raised from 40 °C to 55 °C. Figure 7. van Desmter curves in reduced coordinates for four nitroalkane homologues (nitropropane, black; nitrobutane, red; nitropentane, blue; and nitrohexane, green) separated on the FMS phase. Chromatographic conditions: column dimensions 50 mm × 4.6 mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection volume 0.5 and column temperature 40 °C. No corrections to the plate heights have been made to account for extracolumn dispersion. Reduced Plate Height (h) ° 20 40 60 Reduced Velocity (v) 8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and standard are spiked with a fixed amount of toluene as an internal standard. The following data are obtained: Ppb benzene Peak area benzene Peak area toluene 10.0 252 376 Sample 533 368 What is the concentration of benzene in the sample?arrow_forwardLiquid chromatography has been used to track the concentration of remdesivir (a broad-spectrum antiviral drug, structure shown at right) in COVID patients undergoing experimental treatments. Intensity The authors provide the following details regarding standard solutions preparation: HN CN HO OH NH2 Remdesivir (RDV) stock solution (5000 µg/mL) was prepared by dissolving RDV drug powder using the mixture of DMSO: MeOH (30:70 v/v). The RDV working standard solutions for calibration and quality controls were prepared using methanol in concentrations of 100, 10, 1, 0.1, 0.01 µg/mL. 1, 2.5, 5, 7.5, 10, 25, 50, 75, 100, 250, 500, 1000, and 5000 ng/mL sample solutions were prepared freshly by spiking calibration standard solutions into the blank human plasma samples for method calibration. a) What type of calibration method is being described? Why do you think the authors chose this method as opposed to another? b) Based on the details provided in part a, describe an appropriate method blank…arrow_forward
- Recent advancements in liquid chromatography include the development of ultrahigh pressure liquid chromatography (UHPLC) and an increased use of capillary columns that had previously only been used with gas chromatography. Both of these advances have made the development of portable LC systems possible. For example, Axcend Corp. makes a portable system that uses a capillary column with an internal diameter of 150-μm-that is packed with 1.7-um stationary phase particles. In contrast, a traditional LC column has a 4.6 mm internal diameter and utilizes 5-um stationary phase particles. a) Explain one advantage that is afforded by the use of a capillary column in liquid chromatographic separation. Explain one disadvantage of capillary columns. b) Explain how the use of smaller stationary phase particles can improve the resolution of a separation. Include any relevant equations that support your explanation. c) A scientist at Rowan University is using the Axcend LC to conduct analyses of F…arrow_forwardThis paper describes the use of fullerene molecules, also known as buckyballs, as a stationary phase for liquid chromatography. The performance of the fullerene-modified stationary phase (FMS) is compared to that of a more common C18 stationary phase and to two other carbon-based stationary phases, PGC and COZ. A. 10A OM B. - Figure 1. Idealized drawing of the cross-section of a pore inside a silica particle, showing the relative densities of aminopropylsilyl (red/green) and fullerene (blue) groups: (A) full cross- section; (B) detailed view of covalent bonding of fullerene to the silica surface. Surface densities of silyl and fullerene groups were inferred from elemental composition results obtained at each stage of the synthesis (see Table 1). Absorbance (mAU, 220 nm) 700 600 500 400 300 200 100 a. Define selectivity, a, with words and an equation. b. Explain how the choice of stationary phase affects selectivity. c. Calculate the resolution of the nitrobenzene and toluene peaks in…arrow_forwardNormalized Intensity (a. u.) 0.5 1.0 A 3D-printed GC column (shown below) was created for use with "micro" gas chromatography applications. To prove its utility, it was used to separate a mixture of alkanes (C9-C18, C22, C24). For the separation shown below, the column temperature was ramped from 40 °C to 250 °C at a rate of 30 °C per minute. (a) 9 10 = 1 mm 12 13 15 22 0.0 0 100 200 300 400 Time (sec) a) What detector would you use for this analysis? Justify your selection. b) Explain how the chromatogram would change if the separation was run isothermally. c) Explain how the chromatogram would change if the temperature ramp were increased to 50 °C per minute.arrow_forward
- Devise a synthesis of each compound from the indicated starting material. You may also use any organic compounds with one or two carbons and any needed inorganic reagents. a. Brarrow_forwardPlease help me with #2b & #3 using the data.arrow_forwardHeparin is used as an anti-coagulant. A risk of heparin use is thrombocytopenia, or low platelet count. This risk is minimized with the use of low molecular weight heparins (LMWH), therefore it is desirable to separate LMWH from higher molecular weight heparins. The method of choice to do this is molecular exclusion chromatography. Below is a chromatogram from a molecular exclusion chromatographic run. Peaks ranging from A to J are clearly distinguishable. The heparin mixture that was analyzed had anywhere from 6 to 30 repeat units of monomer (where the heparin with 30 repeat units would be roughly five times the size of the heparin with six repeat units). a. Which letter most likely represents the peak with 6 repeat units given these heparin polymers were separated with molecular exclusion chromatography? b. Explain your reasoning describing the mechanism of retention in molecular exclusion chromatography. 100 80 60 60 Relative Abundance 40 40 E GH 20 20 B A 36 38 40 42 44 46 48 50 50…arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Measurement and Significant Figures; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Gn97hpEkTiM;License: Standard YouTube License, CC-BY
Trigonometry: Radians & Degrees (Section 3.2); Author: Math TV with Professor V;https://www.youtube.com/watch?v=U5a9e1J_V1Y;License: Standard YouTube License, CC-BY