(a) Interpretation: The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined: CH 3 CH 2 CH 2 CH 2 CH 2 OH Concept Introduction: In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H 2 in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H 2 is added across this C=O double bond forming a primary alcohol.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c. (Please provide a full derivation of the equation for x from the equation for I). d) Calculate x for the 1645 cm-1 band

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

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Answer 5

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

Answer 6

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Answer 7

Chapter 16, Problem 16.63P

Interpretation Introduction

(a)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

CH₃CH₂CH₂CH₂CH₂OH

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when an aldehyde is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a primary alcohol.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The carbonyl compound needed to produce the following alcohol by a reduction reaction should be determined:

Concept Introduction:

In a reduction of an organic molecule, either the number of C-O bonds decreases or number of C-H bonds increases. So when a ketone is reduced by H₂ in the presence of Pd catalyst, C=O double bond is reduced to C-O single bond and H₂ is added across this C=O double bond forming a secondary alcohol.

Answer 10

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Answer 12

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Answer 13

Ch. 16.1 - Prob. 16.1P Ch. 16.1 - Draw the structure of the three constitutional...Ch. 16.2 - Prob. 16.3P Ch. 16.2 - Give the structure corresponding to each TUPAC...Ch. 16.2 - Prob. 16.5P Ch. 16.2 - Prob. 16.6P Ch. 16.2 - Give the structure corresponding to each name. a....Ch. 16.3 - Which compound in each pair has the higher boiling...Ch. 16.3 - Acetone and progesterone are two ketones that...Ch. 16.4 - Prob. 16.10P

Solution Summary: The author explains the carbonyl compound needed to produce the following alcohol by a reduction reaction.

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