Videos
Draw all reasonable resonance structures for each species.
a.
b.
c.
d.
e.
f. 
(a)
Interpretation: The possible resonance structure for the given species is to be drawn.
Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.
The delocalization of electrons results in the formation resonance structure.
Answer to Problem 16.32P
The possible resonance structure for the given species is,
Explanation of Solution
The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.
The given species is shown below.
Figure 1
Delocalization of electrons from one position to the other position result in the formation of resonance structure. The resonance structure for the given species is shown below.
Figure 2
The possible resonance structure for the given species is shown in Figure 2.
(b)
Interpretation: The possible resonance structure for the given species is to be drawn.
Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.
The delocalization of electrons results in the formation resonance structure.
Answer to Problem 16.32P
The possible resonance structure for the given species is,
Explanation of Solution
The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance. Carbocation shows resonance structures when double bond is present in conjugation with it.
The given species is shown below.
Figure 3
Delocalization of electrons from one position to the other position result in the formation of resonance structure. The resonance structure for the given species is shown below.
Figure 4
The possible resonance structure for the given species is shown in Figure 4.
(c)
Interpretation: The possible resonance structure for the given species is to be drawn.
Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.
The delocalization of electrons results in the formation resonance structure.
Answer to Problem 16.32P
The possible resonance structure for the given species is,
Explanation of Solution
The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.
The given species is shown below.
Figure 5
Delocalization of electrons from one position to the other position result in the formation of resonance structure. The resonance structure for the given species is shown below.
Figure 6
The possible resonance structure for the given species is shown in Figure 6.
(d)
Interpretation: The possible resonance structure for the given species is to be drawn.
Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.
The delocalization of electrons results in the formation resonance structure.
Answer to Problem 16.32P
The possible resonance structure for the given species is,
Explanation of Solution
The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.
The given species is shown below.
Figure 7
Delocalization of electrons from one position to the other position result in the formation of resonance structure. The resonance structure for the given species is shown below.
Figure 8
The possible resonance structure for the given species is shown in Figure 8.
(e)
Interpretation: The possible resonance structure for the given species is to be drawn.
Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.
The delocalization of electrons results in the formation resonance structure.
Answer to Problem 16.32P
The possible resonance structure for the given species is,
Explanation of Solution
The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.
The given species is shown below.
Figure 9
Delocalization of electrons from one position to the other position result in the formation of resonance structure. The resonance structure for the given species is shown below.
Figure 10
The possible resonance structure for the given species is shown in Figure 10.
(f)
Interpretation: The possible resonance structure for the given species is to be drawn.
Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.
The delocalization of electrons results in the formation resonance structure.
Answer to Problem 16.32P
The possible resonance structure for the given species is,
Explanation of Solution
The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.
The given species is shown below.
Figure 11
Delocalization of electrons from one position to the other position result in the formation of resonance structure. The resonance structure for the given species is shown below.
Figure 12
The possible resonance structure for the given species is shown in Figure 12.
Want to see more full solutions like this?
Chapter 16 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Check the box under each structure in the table that is an enantiomer of the molecule shown below. If none of them are, check the none of the above box under the table. NH ** Molecule 1 NH Molecule 4 none of the above Х Molecule 3 Molecule 2 H N wwwwww.. HN Molecule 5 Molecule 6 HN R mw... N H ☐arrow_forwardNomenclature P4S3 Would this be tetraphsophorus tri sulfide?arrow_forwardDon't used Ai solutionarrow_forward
- Benzene-toluene equilibrium is often approximated as αBT = 2.34. Generate the y-x diagram for this relative volatility. Also, generate the equilibrium data using Raoult’s law, and compare your results to these.arrow_forwardGiven the most probable macrostate: s/k (K) Populations 300 4 200 8 100 16 0 32 Indicate how to demonstrate that the population of the levels is consistent with the Boltzmann distribution.arrow_forwardRank the following components in order of decreasing volatility: butane, n-pentane, iso-pentene (e.g., 3-methyl-1-butene), isoprene, pentanol? Briefly explain your answer.arrow_forward
- Viscosity of a liquid related to the activation energy.arrow_forwardVibrational contributions to internal energy and heat capacity1) are temperature independent2) are temperature dependentarrow_forwardThe approximation of calculating the partition function by integration instead of the summation of all the energy terms can only be done if the separation of the energy levels is much smaller than the product kT. Explain why.arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY