The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted. Concept Introduction: Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons. Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp 2 , sp 3 , sp 3 d, sp 3 d 2 , sp 3 d 3 .

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Answer 1

Question

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

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Answer 2

Question

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

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Answer 3

Question

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

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Answer 4

Question

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

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Answer 5

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

Answer 6

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

Answer 7

Chapter 16, Problem 16.118P

(a)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in ethyl iodide has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The shape around the C-1 and the hybridization of C-1 in transition state has to be predicted.

Concept Introduction:

Molecular geometry: The term molecular geometry refers to the 3-dimensional shape of the molecule by which the molecule is occupying in space with all its surrounding atoms or ions and/or lone pair of electrons.

Hybridization is the phenomenon of intermixing of the atomic orbitals of different energy that results in the formation of a new set of hybrid orbitals which have equivalent energies. The various types of atomic orbitals are: s, p, and d orbitals. Types of hybridization that involves s, p and d orbitals are sp, sp2, sp3, sp3d, sp3d2, sp3d3.

Answer 10

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

Answer 11

(c)

Interpretation Introduction

Interpretation:

While the reaction is run with one of the isomers, the ethyl iodide is not optically active; the reason has to be explained.

Concept Introduction:

Optical isomerism of substituted alkanes:

Optical isomers are non-superimposable mirror images. The carbon atom attached with four different substituents or group of atoms is known as chiral centre/ asymmetric carbon.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16.2 - Balance the following equation and express the...Ch. 16.2 - Prob. 16.1BFP Ch. 16.3 - Prob. 16.2AFP Ch. 16.3 - Prob. 16.2BFP Ch. 16.3 - Find the rate law, the individual and overall...Ch. 16.3 - For the reaction at 0°C, the following data were...Ch. 16.3 - Prob. 16.4AFP Ch. 16.3 - Prob. 16.4BFP Ch. 16.4 - At 25°C, hydrogen iodide breaks down very slowly...Ch. 16.4 - Prob. 16.5BFP

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