The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted. Concept introduction: Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances. Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction . Elementary step: The first step in a reaction mechanism is said to be elementary step. Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

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Answer 1

Question

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.

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Answer 2

Question

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

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Answer 3

Question

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

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Answer 4

Question

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 6

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 7

Chapter 16, Problem 16.113P

(a)

Interpretation Introduction

Interpretation:

The variables that determines whether an alkene will be hydrogenation or dehydrogenated has to be predicted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reactions that requires a higher temperature has to be discussed.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 10

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 11

(c)

Interpretation Introduction

Interpretation:

All the trans-fats arise during hydrogenation of fats that contain some double bonds with a cis-orientation has to be interpreted.

Concept introduction:

Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.

Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a chemical reaction.

Elementary step: The first step in a reaction mechanism is said to be elementary step.

Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16.2 - Balance the following equation and express the...Ch. 16.2 - Prob. 16.1BFP Ch. 16.3 - Prob. 16.2AFP Ch. 16.3 - Prob. 16.2BFP Ch. 16.3 - Find the rate law, the individual and overall...Ch. 16.3 - For the reaction at 0°C, the following data were...Ch. 16.3 - Prob. 16.4AFP Ch. 16.3 - Prob. 16.4BFP Ch. 16.4 - At 25°C, hydrogen iodide breaks down very slowly...Ch. 16.4 - Prob. 16.5BFP

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