College Physics
2nd Edition
ISBN: 9780134601823
Author: ETKINA, Eugenia, Planinšič, G. (gorazd), Van Heuvelen, Alan
Publisher: Pearson,
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Textbook Question
Chapter 16, Problem 15P
Explain using your knowledge of probability why a gas always occupies the entire volume of its container.
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Question 3: In a microcanonical ensemble for 'N' non interacting molecules of an ideal gas in a
specific volume 'V', how can you develop an expression for entropy (S) and change in entropy of the
system if the given system obeys the Boltzmann's statistics. Using the derived value of entropy
formulate an expression for ideal gas equation
Problem 1 The fundamental equation of thermodynamics
for a system is given by
G = NRT--In(T)+
In(o)
where G is Gibbs free energy, N is the number of moles
of chemical substance, R
is gas constant, T
temperature, In is the natural log function, P is pressure.
Please derive an expression each for the following:
is
a. Entropy s
as a function of temperature T,
pressure p, and number of moles N.
b. Volume V as
a function of temperature T,
pressure p, and number of moles N.
c. Helmholtz free energy
as
a
function of
temperature T, pressure p, and number of moles
N.
Describe the difference between a homogeneous and heterogeneous system. Also, provide reasons why modifications to the fundamental thermodynamic equations are necessary.
Chapter 16 Solutions
College Physics
Ch. 16 - Prob. 1RQCh. 16 - Prob. 2RQCh. 16 - Prob. 3RQCh. 16 - Prob. 4RQCh. 16 - Which of the following processes is reversible?...Ch. 16 - In physics the collision of billiard balls is...Ch. 16 - Prob. 3MCQCh. 16 - 4. When driving a car (the system), what object...Ch. 16 - 5. The law of energy conservation says that energy...Ch. 16 - Prob. 6MCQ
Ch. 16 - Entropy can be calculated using which of the...Ch. 16 - Prob. 8MCQCh. 16 - 9. When a drop of ink enters a glass of water and...Ch. 16 - 10. Choose the best reason why the following...Ch. 16 - Prob. 11MCQCh. 16 - Which of the following changes will always...Ch. 16 - Entropy change is easier to determine for...Ch. 16 - 14. Describe five everyday examples of processes...Ch. 16 - Prob. 15CQCh. 16 - 16. In terms of the statistical definition of...Ch. 16 - 17. The entropy of the molecules that form leaves...Ch. 16 - Prob. 18CQCh. 16 - Below, BIO indicates a problem with a biological...Ch. 16 - Below, BIO indicates a problem with a biological...Ch. 16 - Prob. 3PCh. 16 - Below, BIO indicates a problem with a biological...Ch. 16 - Prob. 5PCh. 16 - 6. (a) Identify all of the macrostate...Ch. 16 - 7. * Repeat the previous problem for a system with...Ch. 16 - * Determine the ratio of the number of microstates...Ch. 16 - Prob. 9PCh. 16 - 10. * Parachutists landing on island Parachutists...Ch. 16 - Prob. 11PCh. 16 - * Nine numbered balls are dropped randomly into...Ch. 16 - * Rolling dice Two dice are rolled Macrostates of...Ch. 16 - 14.* (a) Apply your knowledge of probability to...Ch. 16 - Explain using your knowledge of probability why a...Ch. 16 - * EST Estimate the total change in entropy of two...Ch. 16 - 17. * EST (a) You add 0.1 kg of water at of iced...Ch. 16 - * Entropy change of a house A house at 20C...Ch. 16 - 19. ** Barrel of water in cellar in winter A...Ch. 16 - 20. * EST (a) Determine the final temperature when...Ch. 16 - * A 5.0-kg block slides on a level surface and...Ch. 16 - with the horizontal. Determine the entropy change...Ch. 16 - Prob. 23PCh. 16 - * BIO Efficiency of woman walking A 60-kg woman...Ch. 16 - Prob. 25PCh. 16 - 26. ** A cyclic process involving 1 mole of ideal...Ch. 16 - 27. ** A cyclic process involving 1 mole of ideal...Ch. 16 - Prob. 28PCh. 16 - Prob. 29PCh. 16 - Prob. 30PCh. 16 - Prob. 31PCh. 16 - 32. Rank the engines that operate with the...Ch. 16 - 33. Nuclear power plant A nuclear power plant...Ch. 16 - Prob. 34PCh. 16 - Prob. 35GPCh. 16 - W=AUint. W=(3.0)105N/m2 )(0.020m30.010m3)+0...Ch. 16 - * A thermodynamic engine operates between two...Ch. 16 - 38. * A refrigerator transfers 700 J of thermal...Ch. 16 - Prob. 39RPPCh. 16 - Prob. 40RPPCh. 16 - Fuel used to counter air resistance The resistive...Ch. 16 - Prob. 42RPPCh. 16 - Prob. 43RPPCh. 16 - The value of CA for a Ford Escape Hybrid is...
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