Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 1.6, Problem 1.13.1PE
Interpretation Introduction
To determine: The density of Trex in
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
0.29 mol of NaOH is added
to 1.0 L of a 1.2M HCN
solution.
bases:
☑
other:
0.09 mol of HCl is added to
acids:
1.0 L of a solution that is
bases:
0.3M in both HCN and
KCN.
other:
0,0,...
?
00.
18
Ar
日
Chapter 1 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 1.2 - Which of the following is the correct description...Ch. 1.2 - Prob. 1.1.2PECh. 1.5 - Which of the following numbers in your personal...Ch. 1.5 - Practice Exercise 2 The back inside cover of the...Ch. 1.5 - Practice Exercise 1 An object is determined to...Ch. 1.5 - Practice Exercise 2 How many significant figures...Ch. 1.5 - Ellen recently purchased a new hybrid car and...Ch. 1.5 - Practice Exercise 2 It takes 10.5 s for a sprinter...Ch. 1.5 - Prob. 1.5.1PECh. 1.5 - Prob. 1.5.2PE
Ch. 1.6 - Practice Exercise 2 By using a conversion factor...Ch. 1.6 - Practice Exercise 1 Fabiola, who lives in Mexico...Ch. 1.6 - Prob. 1.7.1PECh. 1.6 - Practice Exercise 2 A car travels 28 mi per gallon...Ch. 1.6 - Practice Exercise 2 The surface area of Earth is...Ch. 1.6 - Practice Exercise 1 Composite decking is a...Ch. 1.6 - Prob. 1.9.1PECh. 1.6 - Practice Exercise 2 If the mass of the container...Ch. 1.6 - Practice Exercise 1 Which of the following is the...Ch. 1.6 - Aspirin is composed of 60.0% carbon, 4.5%...Ch. 1.6 - Practice Exercise 1 Which of the following weights...Ch. 1.6 - Practice Exercise 2 How many picometers are there...Ch. 1.6 - Practice Exercise 1 Using Wolfram Alpha...Ch. 1.6 - Practice Exercise 2 Ethylene glycol, the major...Ch. 1.6 - Prob. 1.13.1PECh. 1.6 - Practice Exercise 2 Calculate the density of a...Ch. 1 - The reaction between reactant A (blue spheres) and...Ch. 1 - Prob. 2ECh. 1 - Describe the separation method(s) involved in...Ch. 1 - Prob. 4ECh. 1 - Prob. 5ECh. 1 - Prob. 6ECh. 1 - Prob. 7ECh. 1 - 2447 What are the molecular and empirical formulas...Ch. 1 - When you convert units, how do you decide which...Ch. 1 - Prob. 10ECh. 1 - 2-60 The most common charge associated with...Ch. 1 - Prob. 12ECh. 1 -
2.84 Consider the following organic substances:...Ch. 1 -
2.96 Gallium (Ga) consists of two naturally...Ch. 1 -
2.108 Cyclopropane is an interesting hydrocarbon....Ch. 1 - Write a balanced equation for (a) solid...Ch. 1 - Calculate the molar mass of Ca(NO3)2Ch. 1 - Prob. 18ECh. 1 - Imagine you are working on ways to improve the...Ch. 1 - A key step in balancing chemical equations is...Ch. 1 - a. The characteristic odor of pineapple is due to...Ch. 1 - The complete combustion of octane, Cngs, a...Ch. 1 - Prob. 23ECh. 1 - Prob. 24ECh. 1 -
4.53 Write balanced molecular and net ionic...Ch. 1 - Prob. 26ECh. 1 - Prob. 27ECh. 1 - Prob. 28ECh. 1 -
4.101 Hard water contains Ca2+ , Mg2 + , and Fe2+...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Prob. 32ECh. 1 - Imagine that you are climbing a mountain. Is the...Ch. 1 - A gas is confined to a cylinder under constant...Ch. 1 -
5.100 An aluminum can of a soft drink is placed...Ch. 1 - The hydrocarbons acetylene (C2H2) and benzene...Ch. 1 - The precipitation reaction between AgNO3(aq) and...Ch. 1 - Consider the following three moving objects: a...Ch. 1 - The speed of sound in dry air at 20°C is 343 m/s...Ch. 1 - Prob. 40ECh. 1 - Calculate the energy of a photon of...Ch. 1 - Using Heisenberg's uncertainty principle,...Ch. 1 - Prob. 43ECh. 1 - The following do not represent valid ground-state...Ch. 1 - Prob. 45ECh. 1 - Prob. 46ECh. 1 - Arrange the following atoms and ions in order of...Ch. 1 - Prob. 48ECh. 1 - Prob. 49ECh. 1 - The distance from Grand Rapids, Michigan, to...Ch. 1 - Prob. 51ECh. 1 - Prob. 52ECh. 1 - Prob. 53ECh. 1 - Prob. 54ECh. 1 - Prob. 55ECh. 1 - Which of the these molecules has a Lewis structure...Ch. 1 - Prob. 57ECh. 1 - Write the electron configuration for the element...Ch. 1 - (a) Classify each of the following as a pure...Ch. 1 - Prob. 60AECh. 1 - Prob. 61AECh. 1 - Prob. 62AECh. 1 - Prob. 63AECh. 1 - Prob. 64AECh. 1 - Prob. 65AECh. 1 - Prob. 66AECh. 1 - Prob. 67AECh. 1 - Prob. 68AECh. 1 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 1 - Prob. 70AECh. 1 - The iodine bromide molecule, IBr, is an...Ch. 1 - Prob. 72AECh. 1 - Prob. 73AECh. 1 - Prob. 74AECh. 1 - Prob. 75AECh. 1 - Prob. 76AECh. 1 - Prob. 77AECh. 1 -
10.12 The graph below shows the change in...Ch. 1 - Prob. 79AECh. 1 - Prob. 80AECh. 1 - Prob. 81AECh. 1 - Prob. 82AECh. 1 - Prob. 83AECh. 1 - Prob. 84AECh. 1 - Prob. 85AECh. 1 - Prob. 86AECh. 1 - Prob. 87AECh. 1 - Prob. 88AE
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- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forward
- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. 2.2 mol of NaOH is added to 1.0 L of a 1.4M HF solution. acids: П bases: Х other: ☐ ப acids: 0.51 mol of KOH is added to 1.0 L of a solution that is bases: 1.3M in both HF and NaF. other: ☐ 00. 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: N2O4 (g) 2NO2 (g) AG⁰ = 5.4 kJ Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2O4 tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. yes no 0.42 atm ☑ 5 0/5 ? مله Ararrow_forwardHomework 13 (Ch17) Question 4 of 4 (1 point) | Question Attempt: 2 of 2 ✓ 1 ✓ 2 = 3 4 Time Remaining: 4:25:54 Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction free energy of the following chemical reaction: 2CH3OH (g)+302 (g) → 2CO2 (g) + 4H₂O (g) Round your answer to zero decimal places. ☐ kJ x10 ☐ Subm Check 2020 Hill LLC. All Rights Reserved. Terms of Use | Privacy Cearrow_forward
- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
- € + Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn it into the product of the reaction. Also, write the name of the product molecule under the drawing area. Name: ☐ H C=0 X H- OH HO- H HO- -H CH₂OH ×arrow_forwardDraw the Haworth projection of the disaccharide made by joining D-glucose and D-mannose with a ẞ(1-4) glycosidic bond. If the disaccharide has more than one anomer, you can draw any of them. Click and drag to start drawing a structure. Xarrow_forwardEpoxides can be opened in aqueous acid or aqueous base to produce diols (molecules with two OH groups). In this question, you'll explore the mechanism of epoxide opening in aqueous acid. 2nd attempt Be sure to show all four bonds at stereocenters using hash and wedge lines. 0 0 Draw curved arrows to show how the epoxide reacts with hydronium ion. 100 +1: 1st attempt Feedback Be sure to show all four bonds at stereocenters using hash and wedge lines. See Periodic Table See Hint H A 5 F F Hr See Periodic Table See Hintarrow_forward
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