Chemistry: The Central Science (13th Edition)
Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 16, Problem 106AE

(a) If the core electrons were totally effective at screening the valence electrons and the valence electrons provided no screening for each other, what would be the effective nuclear charge acting on the 3s and 3p valence electrons in P?
(b) Repeat these calculations using Slaters rules.
(c) Detailed calculations indicate that the effective nuclear charge is 5.6 + for the 3s electrons and 4.9 + for the 3p electrons. Why are the values for the 3s and 3p electrons different?
(d) If you remove a single electron from a P atom, which orbital will it come from?

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23. Tin (in group 14) can form both Sn²+ and Snª+ ions, but magnesium (in group 2) forms only Mg²+ ions. (a) Write condensed ground-state electron configurations for the ions Sn²+, Sn++, and Mg²+. (b) Which neutral atoms have ground-state electron configurations identical to Sn²+ and Mg²+? (c) Which 2+ ion is isoelectronic with Sn++?
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Chapter 16 Solutions

Chemistry: The Central Science (13th Edition)

Ch. 16.4 - Prob. 16.6.1PECh. 16.4 - Prob. 16.6.2PECh. 16.4 - Prob. 16.7.1PECh. 16.4 - Prob. 16.7.2PECh. 16.5 - Write a balanced equation for the reaction that...Ch. 16.5 - (a) As described in Section 7.7 , the alkali...Ch. 16.5 - Prob. 16.9.1PECh. 16.5 - Prob. 16.9.2PECh. 16.6 - Arrange each of the following sets of atoms and...Ch. 16.6 - Prob. 16.10.2PECh. 16.6 - In the ionic compoundsLiF,NaCI,KBr, andRbl, the...Ch. 16.6 - Prob. 16.11.2PECh. 16.6 - 7.38 Write equations that show the process for...Ch. 16.6 - Prob. 16.12.2PECh. 16.6 - Prob. 16.13.1PECh. 16.6 - Prob. 16.13.2PECh. 16.6 - (a) What is the trend in first ionization energies...Ch. 16.6 - Prob. 16.14.2PECh. 16.7 - Prob. 16.15.1PECh. 16.7 - Prob. 16.15.2PECh. 16.7 - Prob. 16.16.1PECh. 16.7 - Prob. 16.16.2PECh. 16.8 - Prob. 16.17.1PECh. 16.8 - Write an equation for the second electron affinity...Ch. 16.9 - If the electron affinity for an element is a...Ch. 16.9 - Prob. 16.18.2PECh. 16.9 - 7.52 What is the relationship between the...Ch. 16.9 - Prob. 16.19.2PECh. 16.10 - Prob. 16.20.1PECh. 16.10 - Prob. 16.20.2PECh. 16 - Mercury in the environment can exist in oxidation...Ch. 16 - When magnesium metal is burned in air (Figure 3.6...Ch. 16 - The dipole moment of chlorine monofluoride,...Ch. 16 - Prob. 3ECh. 16 - Consider the element silicon, Si. Write its...Ch. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Which of the these elements is most likely to from...Ch. 16 - Prob. 22ECh. 16 - Which of the following bond is the most polar? H-F...Ch. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Which of the following bonds is the most polar? a....Ch. 16 - Which of the following bonds is most polar: S-Cl,...Ch. 16 - Prob. 29ECh. 16 - How many valence electrons should appear in the...Ch. 16 - Compare the lewis symbol for neon the structure...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Which of the statements about resonance is true?...Ch. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - A portion of a two-dimensional "slab" of NaCl(s)...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Incomplete Lewis structures for the nitrous acid...Ch. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - True or false: The hydrogen atom is most stable...Ch. 16 - Prob. 50ECh. 16 - What is the Lewis symbol for each of the following...Ch. 16 - Using Lewis symbols, diagram the reaction between...Ch. 16 - Use Lewis symbols to represent the reaction that...Ch. 16 - Predict the chemical formula of the ionic compound...Ch. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Is lattice energy usually endothermic or...Ch. 16 - NaCI and KF have the same crystal structure. The...Ch. 16 - Consider the ionic compounds KF, NaCl, NaBr, and...Ch. 16 - Which of the following trends in lattice energy is...Ch. 16 - Energy is required to remove two electrons from Ca...Ch. 16 - Prob. 63ECh. 16 - Use data from Appendix C, Figure 7.10, and Figure...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Using Lewis symbols and Lewis structures, diagram...Ch. 16 - Use Lewis symbols and Lewis structures to diagram...Ch. 16 - Prob. 70ECh. 16 - What is the trend in electronegativity going from...Ch. 16 - Prob. 72ECh. 16 - By referring only to the periodic table, select...Ch. 16 - which of the following bonds are polar? B-F,...Ch. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - In the following pairs of binary compounds,...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Draw the dominant Lewis structure for the...Ch. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - 8.62 For Group 3A-7A elements in the third row of...Ch. 16 - Draw the Lewis structures for each of the...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - 8.66 Describe the molecule xenon trioxide, XeO3,...Ch. 16 - 8.67 There are many Lewis structures you could...Ch. 16 - Prob. 97ECh. 16 - Using Table 8.3, estimate H for each of the...Ch. 16 - Using Table 8.3, estimate H for the following...Ch. 16 - Prob. 100AECh. 16 - Prob. 101AECh. 16 - Prob. 102AECh. 16 - Prob. 103AECh. 16 - Consider the stable elements through lead (Z =...Ch. 16 - 17.80]Figure 7.4 shows the radial probability...Ch. 16 - (a) If the core electrons were totally effective...Ch. 16 - Prob. 107AECh. 16 - Prob. 108AECh. 16 - Prob. 109AECh. 16 - The following observations are made about two...Ch. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - Prob. 113AECh. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116IECh. 16 - Prob. 117IECh. 16 - Prob. 118IECh. 16 - Prob. 119IECh. 16 - Prob. 120IECh. 16 - The electron affinities. in kJ/mol, for the group...Ch. 16 - 7.99 Hydrogen is an unusual element because it...Ch. 16 - Prob. 123IECh. 16 - Prob. 124IECh. 16 - Which of the following is the expected product of...Ch. 16 - Elemental cesium reacts more violently with water...
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