ORGANIC CHEMISTRY W/OWL
9th Edition
ISBN: 9781305717527
Author: McMurry
Publisher: CENGAGE C
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Textbook Question
Chapter 15.SE, Problem 13VC
Give IUPAC names for the following substances (red = O, blue = N):
Expert Solution
Interpretation Introduction
a)
Interpretation:
The IUPAC name of the compound shown is to be given.
Concept introduction:
Compounds with a hydroxyl group attached to the benzene ring are named as derivatives of phenol. Substituted phenols are named using the prefixes ortho (o), meta (m) and para (p). An ortho-substituted phenol has an another substituent in a 1,2-relationship on the ring. A meta-disubstituted phenol has an another substituent in a 1,3-relationship on the ring. A para-disubstituted phenol has another substituent in a 1,4-relationship on the ring.
To give:
The IUPAC name of the compound shown.
Answer to Problem 13VC
The IUPAC name of the compound is m-isopropylphenol.
Explanation of Solution
The compound shown is
It has a hydroxyl and an isopropyl groups in the benzene ring in 1,3-relationship. Therefore its IUPAC name is m-isopropylphenol.
Conclusion
The IUPAC name of the compound is m-isopropylphenol.
Expert Solution
Interpretation Introduction
b)
Interpretation:
The IUPAC name of the compound shown is to be given.
Concept introduction:
Compounds with a carboxyl group attached to the benzene ring are named as derivatives of benzoic acid. Substituted benzoic acids are named using the prefixes ortho (o), meta (m) and para (p). An ortho-substituted benzoic acid has an another substituent in a 1,2-relationship on the ring. A meta-disubstituted benzoic acid has an another substituent in a 1,3-relationship on the ring. A para-disubstituted benzoic acid has another substituent in a 1,4-relationship on the ring.
To give:
The IUPAC name of the compound shown.
Answer to Problem 13VC
The IUPAC name of the compound is o-nitrobenzoic acid.
Explanation of Solution
The compound shown is
It has a carboxyl group and a nitro group in the benzene ring in 1,2-relationship. Therefore its IUPAC name is o-nitrobenzoic acid.
Conclusion
The IUPAC name of the compound is o-nitrobenzoic acid.
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Chapter 15 Solutions
ORGANIC CHEMISTRY W/OWL
Ch. 15.1 - Prob. 1PCh. 15.1 - Give IUPAC names for the following compounds:Ch. 15.1 - Prob. 3PCh. 15.2 - Pyridine is a flat, hexagonal molecule with bond...Ch. 15.3 - Prob. 5PCh. 15.4 - Draw the five resonance structures of the...Ch. 15.4 - Prob. 7PCh. 15.4 - Prob. 8PCh. 15.5 - Prob. 9PCh. 15.5 - Prob. 10P
Ch. 15.6 - Prob. 11PCh. 15.6 - How many electrons does each of the four nitrogen...Ch. 15.SE - Give IUPAC names for the following substances (red...Ch. 15.SE - All-cis cyclodecapentaene is a stable molecule...Ch. 15.SE - 1, 6-Methanonaphthalene has an interesting 1H NMR...Ch. 15.SE - Prob. 16VCCh. 15.SE - Azulene, an isomer of naphthalene, has a...Ch. 15.SE - Give IUPAC names for the following compounds:Ch. 15.SE - Draw structures corresponding to the following...Ch. 15.SE - Prob. 20APCh. 15.SE - Prob. 21APCh. 15.SE - Draw and name all possible aromatic compounds with...Ch. 15.SE - Propose structures for aromatic hydrocarbons that...Ch. 15.SE - Look at the three resonance structures of...Ch. 15.SE - Prob. 25APCh. 15.SE - Prob. 26APCh. 15.SE - Look at the five resonance structures for...Ch. 15.SE - Prob. 28APCh. 15.SE - 3-Chlorocyclopropene, on treatment with AgBF4,...Ch. 15.SE - Prob. 30APCh. 15.SE - Prob. 31APCh. 15.SE - Prob. 32APCh. 15.SE - Which would you expect to be most stable,...Ch. 15.SE - How might you convert 1, 3, 5, 7-cyclononatetraene...Ch. 15.SE - Calicene, like azulene (Problem 15-17), has an...Ch. 15.SE - Pentalene is a most elusive molecule that has been...Ch. 15.SE - Prob. 37APCh. 15.SE - Prob. 38APCh. 15.SE - Compound A, C8H10, yields three substitution...Ch. 15.SE - Prob. 40APCh. 15.SE - Propose structures for compounds that fit the...Ch. 15.SE - Prob. 42APCh. 15.SE - Prob. 43APCh. 15.SE - N-Phenylsydnone, so-named because it was first...Ch. 15.SE - Prob. 45APCh. 15.SE - Prob. 46APCh. 15.SE - Prob. 47APCh. 15.SE - Propose a structure for a molecule C14H12 that has...Ch. 15.SE - The proton NMR spectrum for a compound with...Ch. 15.SE - The proton NMR spectrum of a compound with formula...Ch. 15.SE - Aromatic substitution reactions occur by addition...Ch. 15.SE - Prob. 52APCh. 15.SE - Consider the aromatic anions below and their...Ch. 15.SE - After the reaction below, the chemical shift of Ha...Ch. 15.SE - Prob. 55APCh. 15.SE - Azo dyes are the major source of artificial color...
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