ALEKS 360 AC INTRD CHEM >I<
ALEKS 360 AC INTRD CHEM >I<
5th Edition
ISBN: 9781260977585
Author: BAUER
Publisher: MCG
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Chapter 15, Problem 85QP
Interpretation Introduction

Interpretation:

The nuclear waste formed in a nuclear fission reactor is to be described.

Concept Introduction:

Some of the heavy radioactive nuclides are very much unstable. They undergo decay in two ways, one is alpha decay and another is splitting of the nucleus and a large amount of energy is released. Again some of the heavy nuclides do not undergo fission spontaneously but will undergo if irradiated or bombarded with neutron, When the heavy radioactive nuclides are broken into two or more nucleus by the bombardment with some number of neutrons is called fission reaction. The nuclear waste is the material that nuclear fuel becomes after its use in a fission reactor.

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1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Potential Energy (kJ) 600 400 200 0 -200- -400 -600- -800 (i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s) (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) Ea = 1550 kJ Ea = 2240 kJ (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2350 kJ AH=-950 kJ ΔΗ = 575 ΚΙ AH=-825 kJ a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ Reaction Progress b. What is the overall chemical equation? c. What is the overall change in enthalpy for the above chemical reaction? d. What is the overall amount of activation energy for the above chemical reaction? e. Which reaction intermediate would be considered a catalyst (if any) and why? f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would you be able to make the reaction reverse itself (i.e. have…

Chapter 15 Solutions

ALEKS 360 AC INTRD CHEM >I<

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