ALEKS 360 AC INTRD CHEM >I<
ALEKS 360 AC INTRD CHEM >I<
5th Edition
ISBN: 9781260977585
Author: BAUER
Publisher: MCG
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Chapter 15, Problem 2PP
Interpretation Introduction

Interpretation:

The new nuclide formed is to be identified and the given equation for the nuclear reaction is to be balanced.

Concept Introduction:

In beta emission, a neutron is converted into a proton. So, the mass number remains the same but, atomic number increases by 1. In the process, mass number as well as atomic number is conserved. The total mass number or atomic number of the reactants equals the sum of the mass numbers or atomic numbers of the products.

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Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

Chapter 15 Solutions

ALEKS 360 AC INTRD CHEM >I<

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