(a) Interpretation: The chiral center of the clopidogrel needs to be labeled. Concept introduction: The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

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Answer 1

Question

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

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For a molecule there are 3 energy levels A, B and C, where B is an intermediate energy level between A and C. The A → C transition occurs at 480 nm and the B → C transition occurs at 885 nm. Indicate the wavelength at which the A → B transition will occur.

For a molecule there are three energy levels: A, B and C. If the transition A → B occurs at 1049 nm and the transition B → C occurs at 885 nm, we can say that the wavelength of the transition A → C will occur at approximately:a) 164 nm b) 1934 nm c) 480 nm d) 967 nm

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Answer 2

Question

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

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Answer 3

Question

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

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Answer 4

Question

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

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Answer 5

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

Answer 6

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Answer 7

Chapter 15, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 15.1 - Prob. 15.1P Ch. 15.1 - Prob. 15.1PP Ch. 15.1 - For trans-2-hexene: (a) draw a stereoisomer; (b)...Ch. 15.2 - Prob. 15.3P Ch. 15.2 - Prob. 15.4P Ch. 15.3 - Prob. 15.2PP Ch. 15.3 - Prob. 15.5P Ch. 15.3 - Prob. 15.6P Ch. 15.3 - Prob. 15.3PP Ch. 15.3 - Prob. 15.7P

Solution Summary: The author explains that the chiral center of clopidogrel needs to be labeled.

Concept explainers

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

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Chapter 15 Solutions

Solution Summary: The author explains that the chiral center of clopidogrel needs to be labeled.

Concept explainers

(b) Interpretation: The enantiomers of clopidogrel needs to be drawn. Concept introduction: The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

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Chapter 15 Solutions

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.