EBK INTRODUCTION TO CHEMISTRY
5th Edition
ISBN: 9781260162165
Author: BAUER
Publisher: MCGRAW HILL BOOK COMPANY
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Chapter 15, Problem 48QP
Interpretation Introduction
Interpretation:
The final product of a sequence of decay steps is to be identified.
Concept Introduction:
Some radioactive nuclides go through a series of alpha and beta decay steps to form a stable nuclide. In the process, the mass number as well as the atomic number of the nuclide is conserved. The mass number or atomic number of the reactant equals the sum of the mass numbers or
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2
3
.(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I
Experiment
[1-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
0.000069
4
0.0025
0.0025
0.000140
Calculate the rate constant of this reaction using the table data.
1
2
3
4
I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq)
Experiment
[I-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
Calculate the overall order of this reaction using the table data.
0.0025
0.000069
0.0025
0.000140
H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)·
•••
Experiment [H2 O2]o (M)
[I]o (M) [H+]。 (M)
Initial rate (M/s)
1
0.15
0.15
0.05
0.00012
234
0.15
0.3
0.05
0.00024
0.3
0.15
0.05
0.00024
0.15
0.15
0.1
0.00048
Calculate the overall order of this reaction using the table data.
Chapter 15 Solutions
EBK INTRODUCTION TO CHEMISTRY
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