Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card
Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card
7th Edition
ISBN: 9781337812269
Author: Nivaldo J. Tro
Publisher: Cengage Learning
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Chapter 15, Problem 38E
Interpretation Introduction

Interpretation:

The working of antiperspirant is to be explained.

Concept Introduction:

Body odor is mainly due to the process of perspiration.

Perspiration is the process of sweating from the body, which causes the growth of bacteria.

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2. Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction energies in order to identify the lower energy conformer for each stereoisomer. Based on your calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable. [1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3 CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol) all-cis-1,2,3- 1 all-cis-1,2,4- 2
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What is the mechanism by which the 1,4 product is created?  Please draw it by hand with arrows and stuff.

Chapter 15 Solutions

Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card

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