Concept explainers
Devise a synthesis of each compound from cyclopentane and any other required organic or inorganic reagents.
a. b. c. d. e.
(a)
Interpretation: The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is to be stated.
Concept introduction: Alkenes undergo bromination reaction at primary, secondary and tertiary carbon atom through free radical mechanism on reaction with
Answer to Problem 15.57P
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is,
Figure 1
Explanation of Solution
Cyclopentane is used as a starting material and it converts into bromocyclopentane on treatment with
Figure 1
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is shown in Figure 1.
(b)
Interpretation: The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is to be stated.
Concept introduction: Alkenes undergo bromination reaction at primary, secondary and tertiary carbon atom through free radical mechanism on reaction with
Answer to Problem 15.57P
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is,
Figure 2
Explanation of Solution
In the first step, cyclopentane undergoes bromination when it is treated with
Figure 2
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is shown in Figure 2.
(c)
Interpretation: The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is to be stated.
Concept introduction: Alkenes undergo bromination reaction at primary, secondary and tertiary carbon atom through free radical mechanism on reaction with
Answer to Problem 15.57P
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is,
Figure 3
Explanation of Solution
In the first step, cyclopentane undergoes bromination when it is treated with
Figure 3
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is shown in Figure 3.
(d)
Interpretation: The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is to be stated.
Concept introduction: Alkenes undergo bromination reaction at primary, secondary and tertiary carbon atom through free radical mechanism on reaction with
Answer to Problem 15.57P
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is,
Figure 4
Explanation of Solution
In the first step, cyclopentane undergoes bromination when it is treated with
Figure 4
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is shown in Figure 4.
(e)
Interpretation: The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is to be stated.
Concept introduction: Alkenes undergo bromination reaction at primary, secondary and tertiary carbon atom through free radical mechanism on reaction with
Answer to Problem 15.57P
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is,
Figure 5
Explanation of Solution
In the first step, cyclopentane undergoes bromination when it is treated with
Figure 5
The synthesis of given compound from cyclopentane by the use of any other organic or inorganic reagent is shown in Figure 5.
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Chapter 15 Solutions
ORGANIC CHEMISTRY
- Synthesize each compound from cyclohexanone and organic halides having ≤ 4 C's. You may use any other inorganic reagents.arrow_forwardWhat alkyl halide and nucleophile are needed to prepare each compound?arrow_forwardWhat acetylide anion and alkyl halide are needed to synthesize each alkyne?arrow_forward
- Devise a synthesis of each compound from ethanol (CH3CH2OH) as the only source of carbon atoms. You may use any other organic or inorganic reagents you choose.arrow_forwardDevise a synthesis of each compound. You may use HC=CH, ethylene oxide, and alkyl halides as organic starting materials and any inorganic reagents.arrow_forwardWhat acetylide anion and alkyl halide can be used to prepare each alkyne? Indicate all possibilities when more than one route will work.arrow_forward
- Using ethynylcyclohexane as a starting material and any other needed reagents, how can the following compounds be synthesized?arrow_forwardGive the IUPAC name for each alkyne.arrow_forwardDraw the product formed from the ring-closing metathesis of each compound. Then, devise a synthesis of each metathesis starting material from benzene, alcohols with four or fewer carbons, and any needed organic or inorganic reagents.arrow_forward
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