(a) Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn. Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1 ° , 2 ° or 3 ° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Question

Which of the following is true for a particular reaction if ∆G° is -40.0 kJ/mol at 290 K and –20.0 kJ/mol at 390 K?

Answer 1

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 2

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 3

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 4

Question

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 5

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 6

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 7

Chapter 15, Problem 15.3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 12

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 13

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 14

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Answer 15

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Answer 25

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Prob. 15.7P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains the product formed when a chlorine atom reacts with given species. Free radicals are reactive intermediates formed by the homolysis of covalent bond.

Chapter 15 Solutions