The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified. Concept Introduction: Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid . In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

Question

please draw it for me and tell me where i need to modify the structure

Answer 1

Question

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

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please draw it for me and tell me where i need to modify the structure

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Answer 2

Question

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

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Answer 3

Question

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Expert Solution & Answer

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Answer 4

Question

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Expert Solution & Answer

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Answer 5

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Answer 6

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

Answer 7

Chapter 15, Problem 15.38AP

(a)

Interpretation Introduction

Interpretation:

The cyclopentanone treated with Tollens reagent, Benedict’s reagent it will give positive result or negative result it should be identified.

Concept Introduction:

Oxidation: Generally alcohols can be oxidized to aldehyde or ketone. Aldehyde can be further oxidized to carboxylic acid.

In aldehyde oxidation the hydrogen bonded to the carbonyl carbon is replaced by a hydroxyl group. Moreover ketones do not have this hydrogen, do not react cleanly with oxidizing agents.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The Hexanal treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given molecule (c) treated with Tollens reagent and Benedict’s reagent it will give positive result (or) negative result it should be identified.

Concept Introduction:

Tollens reagent: This test is used in organic chemistry to test for the presence of aldehydes. In this reaction, an aldehyde is oxidized to a carboxylic acid while the Ag+ is reduced to silver metal, which deposits as a thin film on the inner surface of the glass. The generic reaction is as follows and is specific for aldehydes.

Benedict’s reagent: This reagent was extensively used as a test for surges in the urine, which are primarily aldehyde and alpha hydroxyl ketones.

Answer 12

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Ch. 15.1 - Prob. 15.1P Ch. 15.1 - Prob. 15.2P Ch. 15.2 - Draw structures corresponding to the following...Ch. 15.2 - Prob. 15.1CIAP Ch. 15.2 - Prob. 15.2CIAP Ch. 15.2 - Prob. 15.4P Ch. 15.2 - Draw the line structures and provide common names...Ch. 15.2 - Prob. 15.6KCP Ch. 15.3 - For each compound shown next (ad), indicate...Ch. 15.3 - Prob. 15.8KCP

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