Nitric oxide emitted from the engines of supersonic aircraft can contribute to the destruction of stratospheric ozone: N O ( g ) + O 3 ( g ) ⇄ k r k f N O 2 ( g ) + O 2 ( g ) Nitric oxide emissions from supersonic aircraft can contribute to destruction ofthe ozone layer. This reaction is highly exothermic ( Δ H = − 201 k j ) , and its equilibrium constant k c is 3.4 × 10 34 at 300 K. (a) Which rate constant is larger? k f o r k r (b) The value of k f at 300 K is 8.5 × 10 6 M − 1 s − 1 . What is the value of k r at the same temperature?
Nitric oxide emitted from the engines of supersonic aircraft can contribute to the destruction of stratospheric ozone: N O ( g ) + O 3 ( g ) ⇄ k r k f N O 2 ( g ) + O 2 ( g ) Nitric oxide emissions from supersonic aircraft can contribute to destruction ofthe ozone layer. This reaction is highly exothermic ( Δ H = − 201 k j ) , and its equilibrium constant k c is 3.4 × 10 34 at 300 K. (a) Which rate constant is larger? k f o r k r (b) The value of k f at 300 K is 8.5 × 10 6 M − 1 s − 1 . What is the value of k r at the same temperature?
Solution Summary: The author explains the equation for the rate of the reaction for forwarding and reverse reactions.
Nitric oxide emitted from the engines of supersonic aircraft can contribute to the destruction of stratospheric ozone:
N
O
(
g
)
+
O
3
(
g
)
⇄
k
r
k
f
N
O
2
(
g
)
+
O
2
(
g
)
Nitric oxide emissions from supersonic aircraft can contribute to destruction ofthe ozone layer. This reaction is highly exothermic
(
Δ
H
=
−
201
k
j
)
, and its equilibrium constant
k
c
is
3.4
×
10
34
at 300 K. (a) Which rate constant is larger?
k
f
o
r
k
r
(b) The value of
k
f
at 300 K is
8.5
×
10
6
M
−
1
s
−
1
. What is the value of
k
r
at the same temperature?
13
Consider the "C NMR spectrum below.
140
120
100
80
60
40
20
20
PPM
0
The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer.
Check
✓
G
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
Check
×
1
How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
1
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell