CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 15, Problem 15.26A

Solid particles that form in the kidney are called kidney stones and frequently cause acute pain. One common type of kidney stone is formed from a precipitation reaction of calcium and oxalate:
C a 2 + ( a q ) + C 2 O 4 2 ( a q ) C a C 2 O 4 ( s )
Use Le Chatelier’s principle to explain the following statements.

  1. A person taking diuretics, medicines that help kidneys remove fluids, may be atincreased risk for developing kidney stones.
  2. A person diagnosed with hypercalciuria, a genetic condition causing elevated levels of calcium in the urine, has an increased risk for developing kidney stones.
  3. One simple treatment for kidney stones is to avoid foods high in oxalate such as spinach, rhubarb, and nuts.
  4. Another simple treatment for kidney stones is to increase consumption of water.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 15 Solutions

CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT

Ch. 15 - Write the equilibrium constant expression (Kp)...Ch. 15 - APPLY 14.12 Magnesium hydroxide is the active...Ch. 15 - When wine spoils, ethanol is oxidized to acetic...Ch. 15 - The value of K for the dissociation reaction...Ch. 15 - The equilibrium constant K. for the reaction...Ch. 15 - Conceptual APPLY 14.16 The reaction A2 + B2 2...Ch. 15 - PRACTICE 14.17 The H2/CO ratio in mixtures of...Ch. 15 - APPLY 14.18 Calculate the equilibrium...Ch. 15 - PRACTICE 14.19 Calculate the equilibrium...Ch. 15 - APPLY 14.20 Calculate the equilibrium...Ch. 15 - Calculate the equilibrium concentrations of...Ch. 15 - Calculate the equilibrium concentrations of...Ch. 15 - The equilibrium constant Kp , for the reaction...Ch. 15 - The equilibrium constant Kp , for the reaction...Ch. 15 - Consider the equilibrium for the water—gas shift...Ch. 15 - Solid particles that form in the kidney are called...Ch. 15 - Does the number of moles of products...Ch. 15 - CONCEPTUAL APPLY 15.28 The following picture...Ch. 15 - When air is heated at very high temperatures in an...Ch. 15 - Ethyl acetate, a solvent used in many...Ch. 15 - The following pictures represent the composition...Ch. 15 - The following picture represents an equilibrium...Ch. 15 - Nitric oxide emitted from the engines of...Ch. 15 - The energy profile of the reaction krKf is shown....Ch. 15 - Refer to Figure 15.16 to answer the following...Ch. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - Prob. 15.39PCh. 15 - Prob. 15.40PCh. 15 - Prob. 15.41CPCh. 15 - The following pictures represent the equilibrium...Ch. 15 - The reaction A2+BA+AB has an equilibrium constant...Ch. 15 - Prob. 15.44CPCh. 15 - Prob. 15.45CPCh. 15 - Prob. 15.46CPCh. 15 - The following pictures represent equilibrium...Ch. 15 - Prob. 15.48CPCh. 15 - Prob. 15.49CPCh. 15 - Prob. 15.50CPCh. 15 - Prob. 15.51CPCh. 15 - Prob. 15.52SPCh. 15 - Identify the true statement about the...Ch. 15 - Prob. 15.54SPCh. 15 - Prob. 15.55SPCh. 15 - For each of the following equilibria, write the...Ch. 15 - Prob. 15.57SPCh. 15 - Prob. 15.58SPCh. 15 - Prob. 15.59SPCh. 15 - For each of the following equilibria, write the...Ch. 15 - Prob. 15.61SPCh. 15 - The reaction 2AsH3(g)As2(g)+3H2(g) has Kp = 7.2107...Ch. 15 - Prob. 15.63SPCh. 15 - Calculate the value of the equilibrium constant at...Ch. 15 - Prob. 15.65SPCh. 15 - An equilibrium mixture of PCI5, PCi3, and Cl2 at a...Ch. 15 - The partial pressures in an equilibrium mixture of...Ch. 15 - At 298 K, Kc is 2.2105 for the reaction F (g) + O2...Ch. 15 - At 298 K, Kp is 1.6106 for the reaction...Ch. 15 - Prob. 15.70SPCh. 15 - Prob. 15.71SPCh. 15 - Prob. 15.72SPCh. 15 - Prob. 15.73SPCh. 15 - For each of the following equilibria, write the...Ch. 15 - For each of the following equilibria, write the...Ch. 15 - When the following reactions come to equilibrium,...Ch. 15 - Prob. 15.77SPCh. 15 - A chemical engineer is studying reactions to...Ch. 15 - Prob. 15.79SPCh. 15 - At 1400 K, Kc = 103 for the reaction...Ch. 15 - The first step in the industrial synthesis of...Ch. 15 - Phosphine (PH3) decomposes at elevated...Ch. 15 - Prob. 15.83SPCh. 15 - Calculate the equilibrium concentrations of N2O4...Ch. 15 - Calculate the equilibrium concentrations at 25 °C...Ch. 15 - A sample of HI (9.30 103 mol) was placed in an...Ch. 15 - The industrial solvent ethyl acetate is produced...Ch. 15 - Prob. 15.88SPCh. 15 - Prob. 15.89SPCh. 15 - The following reaction, which has Kc = 0.145 at...Ch. 15 - An equilibrium mixture of N2, H2, and NH1 at 700 K...Ch. 15 - An equilibrium mixture of O2 , SO2 , and SO4...Ch. 15 - The air pollutant NO is produced in automobile...Ch. 15 - Prob. 15.94SPCh. 15 - Prob. 15.95SPCh. 15 - Prob. 15.96SPCh. 15 - Prob. 15.97SPCh. 15 - Prob. 15.98SPCh. 15 - The reaction of iron (III) oxide with carbon...Ch. 15 - The equilibrium concentrations in a gas mixture at...Ch. 15 - Prob. 15.101SPCh. 15 - Prob. 15.102SPCh. 15 - Prob. 15.103SPCh. 15 - Prob. 15.104SPCh. 15 - Prob. 15.105SPCh. 15 - At 100 °C, K = 4.72 for the reaction...Ch. 15 - At 25 °C, Kc = 216 for the reaction...Ch. 15 - At 500 °C, F2 , gas is stable and does not...Ch. 15 - Prob. 15.109SPCh. 15 - Phosgene ( COCl2 ) is a toxic gas that damages the...Ch. 15 - Prob. 15.111SPCh. 15 - At 45 °C, Kc = 0.6 19 for the reaction...Ch. 15 - Prob. 15.113SPCh. 15 - Prob. 15.114SPCh. 15 - Prob. 15.115SPCh. 15 - Prob. 15.116SPCh. 15 - Prob. 15.117SPCh. 15 - Consider the following equilibrium:...Ch. 15 - Will the concentration of NO2 increase, decrease,...Ch. 15 - When each of the following equilibria is disturbed...Ch. 15 - Prob. 15.121SPCh. 15 - For the water-gas shift reaction...Ch. 15 - Prob. 15.123SPCh. 15 - Consider the exothermic reaction...Ch. 15 - Prob. 15.125SPCh. 15 - Methanol ( CH3OH ) is manufactured by the reaction...Ch. 15 - In the gas phase at 400°C, isopropyl alcohol...Ch. 15 - The following reaction is important in gold...Ch. 15 - Prob. 15.129SPCh. 15 - The equilibrium constant Kp for the reaction...Ch. 15 - Prob. 15.131SPCh. 15 - Prob. 15.132SPCh. 15 - Consider the following gas-phase reaction:...Ch. 15 - Prob. 15.134SPCh. 15 - Prob. 15.135SPCh. 15 - Prob. 15.136SPCh. 15 - Prob. 15.137SPCh. 15 - Prob. 15.138SPCh. 15 - Prob. 15.139SPCh. 15 - Prob. 15.140SPCh. 15 - Prob. 15.141SPCh. 15 - Prob. 15.142SPCh. 15 - Prob. 15.143SPCh. 15 - Prob. 15.144MPCh. 15 - Prob. 15.145MPCh. 15 - Refining petroleum involves cracking large...Ch. 15 - At 1000 K, Kp = 2.1 106 and H ° = -107.7 kJ for...Ch. 15 - Consider the gas-phase decomposition of...Ch. 15 - Prob. 15.149MPCh. 15 - Prob. 15.150MPCh. 15 - Prob. 15.151MPCh. 15 - Prob. 15.152MPCh. 15 - Prob. 15.153MPCh. 15 - Prob. 15.154MPCh. 15 - A 125.4 g quantity of water and an equal molar...Ch. 15 - Prob. 15.156MPCh. 15 - Prob. 15.157MPCh. 15 - Prob. 15.158MPCh. 15 - Prob. 15.159MPCh. 15 - Ozone is unstable with respect to decomposition to...Ch. 15 - Prob. 15.161MPCh. 15 - For the decomposition reaction...Ch. 15 - Prob. 15.163MP
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