The given radicals are to be ranked in order of increasing stability. Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

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Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

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Part 1. Draw monomer units of the following products and draw their reaction mechanism (with arrow pushing) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate

Answer 2

Question

Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

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Answer 3

Question

Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

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Answer 4

Question

Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

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Answer 5

Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

Answer 6

Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

Answer 7

Chapter 15, Problem 15.31P

Interpretation Introduction

Interpretation: The given radicals are to be ranked in order of increasing stability.

Concept introduction: When one alkyl group is linked to the carbon radical, then the radical is termed as primary radical. When two alkyl groups are linked to the carbon radical, the radical is termed as secondary radical and when three alkyl groups are linked to the carbon radical, the radical is termed as tertiary radical.

Answer 8

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Answer 11

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Prob. 15.7P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that tertiary radical is more stable than secondary radical and primary radical. Allyl and benzylic radicals are stabilized by the resonance.

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Chapter 15 Solutions