(a) Interpretation: The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram. Concept introduction: An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Question

Want to see the full answer?

Answer 1

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Is nucleophilic acyl substitution an SN1 or SN2 reaction?

Draw product A, indicating what type of reaction occurs. NH2 F3C CF3 NH OMe NH2-NH2, ACOH A

Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Answer 2

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Answer 6

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 7

Chapter 15, Problem 15.25P

Interpretation Introduction

(a)

Interpretation:

The molecular orbital that holds the “extra electrons” in allyl anion is to be identified by using the molecular orbital diagram.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable as compared to branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The carbon atom that bears the negative charge is to be identified according to the molecular orbital description.

Concept introduction:

An allylic carbocation is a positively charged carbocation which is adjacent to a double bond. This carbocation is considered to be more stable than branched non allylic alkyl carbocation allylic carbocations are stable because of their electronic structures.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Answer 11

Interpretation Introduction

(c)

Interpretation:

The same conclusion is to be shown by drawing resonance structures of allyl anion.

Concept introduction:

Resonance structures represent the delocalization of electrons. It is considered as a stabilizing effect. The energy associated with electron delocalization is known as resonance energy

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Prob. 15.3P Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Prob. 15.6P Ch. 15 - Prob. 15.7P Ch. 15 - Prob. 15.8P Ch. 15 - Prob. 15.9P Ch. 15 - Prob. 15.10P

Solution Summary: The author explains the molecular orbital that holds the "extra electrons" in allyl anion.

Concept explainers

Want to see the full answer?

Chapter 15 Solutions