FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
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Chapter 15, Problem 15.20UKC

(a)

Interpretation Introduction

Interpretation:

The target molecule transformation should be draw and identified given the starting molecule of aldehyde under the reduction process.

Concept Introduction:

Oxidation Reaction: Generally alcohol can be oxidizing to aldehyde or ketone and aldehyde can be further oxidized to carboxylic acids.

Reduction Reaction: This process in which any substance atoms, ion or molecule gains one or more electrons it is called reduction.

(a)

Expert Solution
Check Mark

Answer to Problem 15.20UKC

The hydride added to the carbonyl carbon, the polar (C=O) carbon has a partial positive charge, then the reduction process has

FUND.OF GEN CHEM CHAP 1-13 W/ACCESS, Chapter 15, Problem 15.20UKC , additional homework tip  1

Explanation of Solution

Reduction reaction: The given carbonyl molecule is converted into alcohol (b) in this undergoes for reduction process was occurred. The hydride ion added to the carbonyl carbon, because carbonyl carbon is polar it as partial positive charges in carbon atom.

FUND.OF GEN CHEM CHAP 1-13 W/ACCESS, Chapter 15, Problem 15.20UKC , additional homework tip  2

(b)

Interpretation Introduction

To determine give the reactions indicate which direction represents reduction and which represents oxidation.

Concept Introduction:

Carbonyl group: This group presence of a (C=O) distinguished carbonyl compounds other organic compounds, carbonyl compounds are then classified according to what is bonded to the carbonyl carbon.

Oxidation Reaction: Generally alcohol can be oxidizing to aldehyde or ketone and aldehyde can be further oxidized to carboxylic acids.

Reduction Reaction: This process in which any substance atoms, ion or molecule gains one or more electrons it is called reduction.

(b)

Expert Solution
Check Mark

Answer to Problem 15.20UKC

Given the arrow to the right represents reduction and the arrow to the left represents oxidation.

FUND.OF GEN CHEM CHAP 1-13 W/ACCESS, Chapter 15, Problem 15.20UKC , additional homework tip  3

Explanation of Solution

Let us consider given reaction,

FUND.OF GEN CHEM CHAP 1-13 W/ACCESS, Chapter 15, Problem 15.20UKC , additional homework tip  4

Given the arrow to the right represents reduction and the arrow to the left represents oxidation.

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Chapter 15 Solutions

FUND.OF GEN CHEM CHAP 1-13 W/ACCESS

Ch. 15.4 - Prob. 15.9KCPCh. 15.5 - Indicate whether the following compounds will give...Ch. 15.6 - Draw line structures of the following compounds...Ch. 15.6 - Prob. 15.12PCh. 15.7 - Prob. 15.13PCh. 15.7 - Prob. 15.14PCh. 15.7 - Prob. 15.15PCh. 15.7 - Draw the structure of each acetal or ketal final...Ch. 15.7 - Prob. 15.17PCh. 15.7 - Prob. 15.18PCh. 15.7 - Prob. 15.19PCh. 15.7 - Prob. 15.1MRPCh. 15.7 - Prob. 15.2MRPCh. 15.7 - Prob. 15.3MRPCh. 15.7 - Prob. 15.3CIAPCh. 15.7 - (a) What are mirotubules? (b) Why would drugs that...Ch. 15.7 - Tetrodotoxin, found in the puffer fish, has been...Ch. 15 - Prob. 15.20UKCCh. 15 - Prob. 15.21UKCCh. 15 - Prob. 15.22UKCCh. 15 - Prob. 15.23UKCCh. 15 - Prob. 15.24UKCCh. 15 - Prob. 15.25UKCCh. 15 - ALDEHYDESAND KETONES (SECTIONS 15.1 AND 15.2)...Ch. 15 - Draw a structure for a compound that meets each of...Ch. 15 - Prob. 15.28APCh. 15 - Prob. 15.29APCh. 15 - Draw structures corresponding to the following...Ch. 15 - Draw structures corresponding to the following...Ch. 15 - Prob. 15.32APCh. 15 - Prob. 15.33APCh. 15 - The following names are incorrect. What is wrong...Ch. 15 - Prob. 15.35APCh. 15 - Prob. 15.36APCh. 15 - Prob. 15.37APCh. 15 - Prob. 15.38APCh. 15 - Prob. 15.39APCh. 15 - Prob. 15.40APCh. 15 - Draw the structures of the aldehydes that might be...Ch. 15 - Write the structures of the hemiacetal or...Ch. 15 - Write the structures of the hemiacetal or...Ch. 15 - Prob. 15.44APCh. 15 - Prob. 15.45APCh. 15 - Prob. 15.46APCh. 15 - Prob. 15.47APCh. 15 - Prob. 15.48APCh. 15 - Prob. 15.49APCh. 15 - Prob. 15.50CPCh. 15 - Prob. 15.51CPCh. 15 - Prob. 15.52CPCh. 15 - Prob. 15.53CPCh. 15 - Prob. 15.54CPCh. 15 - Name the following compounds: (a) (b) (c) (be sure...Ch. 15 - Draw the structural formulas of the following...Ch. 15 - Prob. 15.57CPCh. 15 - Complete the following equations (refer to Summary...Ch. 15 - Prob. 15.59CPCh. 15 - How could you differentiate between 3-hexanol and...Ch. 15 - The liquids 1-butanol and butanal have similar...Ch. 15 - Prob. 15.62CPCh. 15 - Prob. 15.63GPCh. 15 - Prob. 15.64GPCh. 15 - Using the ketone structural form of fructose...Ch. 15 - Prob. 15.66GP
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