GENERAL,ORGANIC,+BIOCHEMISTRY
GENERAL,ORGANIC,+BIOCHEMISTRY
10th Edition
ISBN: 9781260148954
Author: Denniston
Publisher: RENT MCG
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Chapter 15, Problem 15.11QP
Interpretation Introduction

Interpretation:

The boiling point of amines, alkanes, and alcohols with the same molecular mass has to be compared.

Expert Solution & Answer
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Explanation of Solution

Amines contains nitrogen atom as well hydrogen atoms, among them nitrogen is more electronegative.  So, the polar NH bond and hydrogen bonds occur between primary amine and secondary amines and due to this, amines have higher boiling point than alkanes, which are non-polar.  Comparatively OH bond is more polar in nature to NH bond and alcohols exhibits intermolecular hydrogen bonding and which is stronger than the intermolecular hydrogen bonding between primary amine and secondary amine.  Hence, alcohols has higher boiling point than amines and alkanes.  The increasing trend of boiling point among alkanes, amines and alcohols is,

    alkanes < amines < alcohols

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Chapter 15 Solutions

GENERAL,ORGANIC,+BIOCHEMISTRY

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