Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Question
Chapter 15, Problem 15.119QE
Interpretation Introduction
Interpretation:
The mass of benzoic acid that must be dissolved to make
Concept Introduction:
The dilution formula is given as follows:
Here,
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 15 Solutions
Chemistry: Principles and Practice
Ch. 15 - Prob. 15.1QECh. 15 - Can a compound be an Arrhenius base and not a...Ch. 15 - Water is not the only solvent that undergoes...Ch. 15 - Write two BrnstedLowry acid-base reactions and...Ch. 15 - Define pH and explain why pH, rather than...Ch. 15 - Prob. 15.6QECh. 15 - Prob. 15.7QECh. 15 - Prob. 15.8QECh. 15 - Prob. 15.9QECh. 15 - Prob. 15.10QE
Ch. 15 - Prob. 15.11QECh. 15 - Prob. 15.12QECh. 15 - Why have chemists not tabulated the fraction...Ch. 15 - Prob. 15.15QECh. 15 - Prob. 15.16QECh. 15 - Prob. 15.17QECh. 15 - Prob. 15.18QECh. 15 - Define oxyacid and give examples from among the...Ch. 15 - Prob. 15.20QECh. 15 - Prob. 15.21QECh. 15 - Prob. 15.22QECh. 15 - Prob. 15.23QECh. 15 - Prob. 15.24QECh. 15 - Prob. 15.25QECh. 15 - Write the formula and name for the conjugate acid...Ch. 15 - For each of the following reactions, identify the...Ch. 15 - Prob. 15.28QECh. 15 - Prob. 15.29QECh. 15 - Prob. 15.30QECh. 15 - Prob. 15.31QECh. 15 - Write an equation to describe the proton transfer...Ch. 15 - Prob. 15.33QECh. 15 - Determine the hydrogen ion or hydroxide ion...Ch. 15 - Prob. 15.35QECh. 15 - The hydroxide ion concentrations in wines actually...Ch. 15 - Prob. 15.37QECh. 15 - Prob. 15.38QECh. 15 - Prob. 15.39QECh. 15 - Prob. 15.40QECh. 15 - Prob. 15.41QECh. 15 - Prob. 15.42QECh. 15 - Prob. 15.43QECh. 15 - Prob. 15.44QECh. 15 - Prob. 15.45QECh. 15 - Prob. 15.46QECh. 15 - A saturated solution of milk of magnesia, Mg(OH)2,...Ch. 15 - Find [OH] and the pH of the following solutions....Ch. 15 - Write the chemical equation for the ionization of...Ch. 15 - Prob. 15.50QECh. 15 - Prob. 15.51QECh. 15 - Prob. 15.52QECh. 15 - Prob. 15.53QECh. 15 - Assuming that the conductivity of an acid solution...Ch. 15 - Prob. 15.55QECh. 15 - Prob. 15.56QECh. 15 - Prob. 15.57QECh. 15 - Prob. 15.58QECh. 15 - Prob. 15.59QECh. 15 - A 0.10 M solution of chloroacetic acid, ClCH2COOH,...Ch. 15 - Prob. 15.61QECh. 15 - Prob. 15.62QECh. 15 - Prob. 15.63QECh. 15 - Prob. 15.64QECh. 15 - Prob. 15.65QECh. 15 - Prob. 15.66QECh. 15 - Prob. 15.67QECh. 15 - Prob. 15.68QECh. 15 - Write the chemical equation for the ionization of...Ch. 15 - Prob. 15.70QECh. 15 - Hydrazine, N2H4, is weak base with Kb = 1.3 106....Ch. 15 - Prob. 15.72QECh. 15 - Prob. 15.73QECh. 15 - Prob. 15.74QECh. 15 - Calculate the [OH] and the pH of a 0.024 M...Ch. 15 - Prob. 15.76QECh. 15 - Prob. 15.77QECh. 15 - Prob. 15.78QECh. 15 - Prob. 15.79QECh. 15 - Prob. 15.80QECh. 15 - Find the value of Kb for the conjugate base of the...Ch. 15 - Consider sodium acrylate, NaC3H3O2. Ka for acrylic...Ch. 15 - Prob. 15.83QECh. 15 - Prob. 15.84QECh. 15 - Prob. 15.85QECh. 15 - Prob. 15.86QECh. 15 - Prob. 15.87QECh. 15 - Prob. 15.88QECh. 15 - Prob. 15.89QECh. 15 - Prob. 15.90QECh. 15 - Prob. 15.91QECh. 15 - Prob. 15.92QECh. 15 - Prob. 15.93QECh. 15 - Prob. 15.94QECh. 15 - Explain how to calculate the pH of a solution that...Ch. 15 - Prob. 15.96QECh. 15 - Prob. 15.97QECh. 15 - Prob. 15.98QECh. 15 - Hypofluorous acid, HOF, is known, but fluorous...Ch. 15 - Prob. 15.100QECh. 15 - Prob. 15.101QECh. 15 - Prob. 15.102QECh. 15 - Which of each pair of acids is stronger? Why? (a)...Ch. 15 - Prob. 15.104QECh. 15 - Prob. 15.105QECh. 15 - Prob. 15.106QECh. 15 - Prob. 15.107QECh. 15 - Prob. 15.108QECh. 15 - Prob. 15.109QECh. 15 - Prob. 15.110QECh. 15 - Prob. 15.111QECh. 15 - Prob. 15.112QECh. 15 - Prob. 15.113QECh. 15 - Prob. 15.114QECh. 15 - Prob. 15.115QECh. 15 - Prob. 15.116QECh. 15 - Prob. 15.117QECh. 15 - Prob. 15.118QECh. 15 - Prob. 15.119QECh. 15 - Prob. 15.120QECh. 15 - A solution is made by diluting 25.0 mL of...Ch. 15 - A Liquid HF undergoes an autoionization reaction:...Ch. 15 - Pure liquid ammonia ionizes in a manner similar to...Ch. 15 - Prob. 15.124QECh. 15 - Prob. 15.125QECh. 15 - Prob. 15.126QECh. 15 - Prob. 15.127QECh. 15 - Prob. 15.128QECh. 15 - An aqueous solution contains formic acid and...Ch. 15 - A solution is made by dissolving 15.0 g sodium...Ch. 15 - Calculate the pH of a solution prepared by adding...Ch. 15 - Prob. 15.132QECh. 15 - Prob. 15.133QECh. 15 - When perchloric acid ionizes, it makes the...Ch. 15 - Prob. 15.135QE
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