
Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Question
Chapter 15, Problem 114CP
Interpretation Introduction
Interpretation:
The reason for one stoichiometric point in both the experiments is to be justified.
Concept introduction:
Titration is a technique used in quantitative
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 15 Solutions
Chemistry
Ch. 15 - What is meant by the presence of a common ion? How...Ch. 15 - Define a buffer solution. What makes up a buffer...Ch. 15 - One of the most challenging parts of solving...Ch. 15 - A good buffer generally contains relatively equal...Ch. 15 - Draw the general titration curve for a strong acid...Ch. 15 - Instead of the titration of a strong acid by a...Ch. 15 - Sketch the titration curve for a weak acid...Ch. 15 - Sketch the titration curve for a weak base...Ch. 15 - What is an acidbase indicator? Define the...Ch. 15 - Why does an indicator change from its acid color...
Ch. 15 - What are the major species in solution after...Ch. 15 - A friend asks the following: Consider a buffered...Ch. 15 - Mixing together solutions of acetic acid and...Ch. 15 - Could a buffered solution be made by mixing...Ch. 15 - Sketch two pH curves, one for the titration of a...Ch. 15 - Sketch a pH curve for the titration of a weak acid...Ch. 15 - You have a solution of the weak acid HA and add...Ch. 15 - You have a solution of the weak acid HA and add...Ch. 15 - The common ion effect for weak acids is to...Ch. 15 - Prob. 10QCh. 15 - A best buffer has about equal quantities of weak...Ch. 15 - Consider the following pH curves for 100.0 mL of...Ch. 15 - An acid is titrated with NaOH. The following...Ch. 15 - Consider the following four titrations. i. 100.0...Ch. 15 - Figure 14-4 shows the pH curves for the titrations...Ch. 15 - Acidbase indicators mark the end point of...Ch. 15 - How many of the following are buffered solutions?...Ch. 15 - Which of the following can be classified as buffer...Ch. 15 - A certain buffer is made by dissolving NaHCO3 and...Ch. 15 - A buffer is prepared by dissolving HONH2 and...Ch. 15 - Calculate the pH of each of the following...Ch. 15 - Calculate the pH of each of the following...Ch. 15 - Compare the percent dissociation of the acid in...Ch. 15 - Compare the percent ionization of the base in...Ch. 15 - Calculate the pH after 0.020 mole of HCl is added...Ch. 15 - Calculate the pH after 0.020 mole of HCl is added...Ch. 15 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 15 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 15 - Which of the solutions in Exercise 21 shows the...Ch. 15 - Prob. 30ECh. 15 - Calculate the pH of a solution that is 1.00 M HNO2...Ch. 15 - Calculate the pH of a solution that is 0.60 M HF...Ch. 15 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 15 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 15 - Calculate the pH of each of the following buffered...Ch. 15 - Calculate the pH of each of the following buffered...Ch. 15 - Calculate the pH of a buffered solution prepared...Ch. 15 - A buffered solution is made by adding 50.0 g NH4Cl...Ch. 15 - Calculate the pH after 0.010 mole of gaseous HCl...Ch. 15 - An aqueous solution contains dissolved C6H5NH3Cl...Ch. 15 - Calculate the mass of sodium acetate that must be...Ch. 15 - What volumes of 0.50 M HNO2 and 0.50 M NaNO2 must...Ch. 15 - Consider a solution that contains both C5H5N and...Ch. 15 - Calculate the ratio [NH3]/[NH4+] in...Ch. 15 - Carbonate buffers are important in regulating the...Ch. 15 - When a person exercises, muscle contractions...Ch. 15 - Consider the acids in Table 13-2. Which acid would...Ch. 15 - Consider the bases in Table 13-3. Which base would...Ch. 15 - Calculate the pH of a solution that is 0.40 M...Ch. 15 - Calculate the pH of a solution that is 0.20 M HOCl...Ch. 15 - Which of the following mixtures would result in...Ch. 15 - Which of the following mixtures would result in a...Ch. 15 - What quantity (moles) of NaOH must be added to 1.0...Ch. 15 - Calculate the number of moles of HCl(g) that must...Ch. 15 - Consider the titration of a generic weak acid HA...Ch. 15 - Sketch the titration curve for the titration of a...Ch. 15 - Consider the titration of 40.0 mL of 0.200 M HClO4...Ch. 15 - Consider the titration of 80.0 mL of 0.100 M...Ch. 15 - Consider the titration of 100.0 mL of 0.200 M...Ch. 15 - Consider the titration of 100.0 mL of 0.100 M...Ch. 15 - Lactic acid is a common by-product of cellular...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Calculate the pH at the halfway point and at the...Ch. 15 - In the titration of 50.0 mL of 1.0 M methylamine,...Ch. 15 - You have 75.0 mL of 0.10 M HA. After adding 30.0...Ch. 15 - A student dissolves 0.0100 mole of an unknown weak...Ch. 15 - Two drops of indicator HIn (Ka = 1.0 109), where...Ch. 15 - Methyl red has the following structure: It...Ch. 15 - Potassium hydrogen phthalate, known as KHP (molar...Ch. 15 - A certain indicator HIn has a pKa of 3.00 and a...Ch. 15 - Which of the indicators in Fig. 14-8 could be used...Ch. 15 - Prob. 74ECh. 15 - Which of the indicators in Fig. 14-8 could be used...Ch. 15 - Prob. 76ECh. 15 - Estimate the pH of a solution in which bromcresol...Ch. 15 - Estimate the pH of a solution in which crystal...Ch. 15 - A solution has a pH of 7.0. What would be the...Ch. 15 - A solution has a pH of 4.5. What would be the...Ch. 15 - Derive an equation analogous to the...Ch. 15 - a. Calculate the pH of a buffered solution that is...Ch. 15 - Tris(hydroxymethyl)aminomethane, commonly called...Ch. 15 - You make 1.00 L of a buffered solution (pH = 4.00)...Ch. 15 - You have the following reagents on hand: Solids...Ch. 15 - Prob. 86AECh. 15 - Phosphate buffers are important in regulating the...Ch. 15 - What quantity (moles) of HCl(g) must be added to...Ch. 15 - Prob. 89AECh. 15 - The following plot shows the pH curves for the...Ch. 15 - Calculate the volume of 1.50 102 M NaOH that must...Ch. 15 - Prob. 92AECh. 15 - A certain acetic acid solution has pH = 2.68....Ch. 15 - A 0.210-g sample of an acid (molar mass = 192...Ch. 15 - The active ingredient in aspirin is...Ch. 15 - One method for determining the purity of aspirin...Ch. 15 - A student intends to titrate a solution of a weak...Ch. 15 - A student titrates an unknown weak acid, HA, to a...Ch. 15 - A sample of a certain monoprotic weak acid was...Ch. 15 - Consider 1.0 L of a solution that is 0.85 M HOC6H5...Ch. 15 - What concentration of NH4Cl is necessary to buffer...Ch. 15 - Consider the following acids and bases: HCO2H Ka =...Ch. 15 - Consider a buffered solution containing CH3NH3Cl...Ch. 15 - Consider the titration of 150.0 mL of 0.100 M HI...Ch. 15 - Consider the titration of 100.0 mL of 0.100 M HCN...Ch. 15 - Consider the titration of 100.0 mL of 0.200 M...Ch. 15 - Consider the following four titrations (iiv): i....Ch. 15 - Another way to treat data from a pH titration is...Ch. 15 - A buffer is made using 45.0 mL of 0.750 M HC3H5O2...Ch. 15 - A 0.400-M solution of ammonia was titrated with...Ch. 15 - What volume of 0.0100 M NaOH must be added to 1.00...Ch. 15 - Consider a solution formed by mixing 50.0 mL of...Ch. 15 - When a diprotic acid. H2A. is titrated with NaOH,...Ch. 15 - Prob. 114CPCh. 15 - The titration of Na2CO3 with HCl bas the following...Ch. 15 - Consider the titration curve in Exercise 115 for...Ch. 15 - A few drops of each of the indicators shown in the...Ch. 15 - Malonic acid (HO2CCH2CO2H) is a diprotic acid. In...Ch. 15 - A buffer solution is prepared by mixing 75.0 mL of...Ch. 15 - A 10.00-g sample of the ionic compound NaA, where...Ch. 15 - Calculate the pH of a solution prepared by mixing...Ch. 15 - Consider a solution prepared by mixing the...
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