A plausible mechanism for the reaction:
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- Why awe elementary reactions involving three or more reactants very uncommon?arrow_forwardWhen every collision between reactants leads to a reaction, what determines the rate at which the reaction occurs?arrow_forwardAccount for the relationship between the rate of a reaction and its activation energy.arrow_forward
- The reaction H2SeO3(aq) + 6I-(aq) + 4H+(aq) Se(s) + 2I-3(aq) + 3H2O(l) was studied at 0C, and the following data were obtained: [H2SeO3]0 (mol/L) [H+]0 (mol/L) [I]0(mol/L) Initial Rate (mol/L s) 1.0 104 2.0 102 2.0 102 1.66 107 2.0 104 2.0 102 2.0 10-2 3.33 107 3.0 104 2.0 102 2.0 102 4.99 107 1.0 104 4.0 102 2.0 102 6.66 107 1.0 104 1.0 102 2.0 102 0.42 107 1.0 104 2.0 102 4.0 102 13.2 107 1.0 104 1.0 102 4.0 102 3.36 107 These relationships hold only if there is a very small amount of I3 present. What is the rate law and the value of the rate constant? (Assumethatrate=[H2SeO3]t)arrow_forwardA reaction is believed to occur by the following mechanism: Stepl: 2AI (Fast equilibrium) Step 2: I + B C (Slow) Overall: 2 A + B C What experimentally determined rate law would lead to this mechanism? (a) Rate = k[A][B] (b) Rate = k[A]2[B] (c) Rate = k[A]2 (d) Rate = k[I][B]arrow_forwardFor the reaction of crystal violet with NaOH(aq), the measured rate of reaction is 1.27 106 mol L1 s1 when the concentration of crystal violet cation is 4.13 105 mol/L. (a) Estimate how long it will take for the concentration of crystal violet to drop from 4.30 105 mol/L to 3.96 105 mol/L. (b) Could you use the same method to make an accurate estimate of how long it would take for the concentration of crystal violet to drop from 4.30 105 mol/L to 0.43 105 mol/L? Explain why or why not.arrow_forward
- Ozone, O3, in the Earths upper atmosphere decomposes according to the equation 2 O3(g) 3 O2(g) The mechanism of the reaction is thought to proceed through an initial fast, reversible step followed by a slow, second step. Step 1: Fast, reversible O3(g) O2(g) + O(g) Step 2: Slow O3(g) + O(g) 2 O2(g) (a) Which of the steps is rate-determining? (b) Write the rate equation for the rate-determining steparrow_forwardIn general, can we predict the effect of doubling the concentration of A on the rate of the overall reaction A+BC? Can we predict the effect if the reaction is known to be an elementary reaction?arrow_forward. Account for the increase in reaction rate brought about by a catalyst.arrow_forward
- The following statements relate to the reaction for the formation of HI: H2(g) + I2(g) -* 2 HI(g) Rate = it[HJ [I2J Determine which of the following statements are true. If a statement is false, indicate why it is incorrect. The reaction must occur in a single step. This is a second-order reaction overall. Raising the temperature will cause the value of k to decrease. Raising the temperature lowers the activation energy' for this reaction. If the concentrations of both reactants are doubled, the rate will double. Adding a catalyst in the reaction will cause the initial rate to increase.arrow_forwardConsider the following statements: In general, the rate of a chemical reaction increases a bit at first because it takes a while for the reaction to get warmed up. After that, however, the rate of the reaction decreases because its rate is dependent on the concentrations of the reactants, and these are decreasing. Indicate everything that is correct in these statements, and indicate everything that is incorrect. Correct the incorrect statements and explain.arrow_forwardRank the following in order of increasing reaction rate. (a) Dynamite exploding (b) Iron rusting (c) Paper burningarrow_forward
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