CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 14, Problem 77AP
The following diagrams represent the progress of the reaction a
molecules and the green spheres represent B molecules. Calculate the rate constant of the reaction.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Finish the reactions
hand written please
Part A
Identify each alcohol as primary, secondary, or tertiary
Drag the appropriate items to their respective bins.
CH₂
H₂C-
-C-OH
HO
CH₂
Primary
Он
OH
CH₂
OH
CCH₂OH
CH₂
сн
Secondary
Tertiary
Reset Help
CH,CH₂
(CH)CHCH,OH CH,CH,CH,CCH,
CHOH
CH₂
Different types of alcohol groups
Alcohol and its reaction:
8. Combing two alcohol molecules below and completing the reaction with
Product .( Hint Reaction called etherification as ether is formed and name the
ether once you complete the reaction.
Hint.:
R-O-H+H-O-RR-O-R
Do the reaction:
CH₂OH + CH₂OH---→
+ H-O-H
9. Write the reaction of formation of alcohol from alkene by adding water:
Addition reaction also called hydration reaction as we are adding water
which occur always in presence of acid
Hint: Break the double bond and add H and OH if symmetrical then
add anywhere if unsymmetrical then follow Markovnikov rule H
should go to that double bone carbon which has more hydrogen
CH2=CH2 + H₂O-→
Complete the reaction
hand written please
Chapter 14 Solutions
CHEMISTRY >CUSTOM<
Ch. 14.1 - Practice Problem ATTEMPT
Write the rate...Ch. 14.1 - Practice ProblemBUILD Write the balanced equation...Ch. 14.1 - Prob. 1PPCCh. 14.1 - 14.1.1 Which expressions are correct for the rate...Ch. 14.1 - 14.1.2 In the same reaction:
if the concentration...Ch. 14.2 - Practice Problem ATTEMPT Consider the reaction:...Ch. 14.2 - Practice Problem BUILD Consider the following...Ch. 14.2 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...
Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...Ch. 14.2 - 14.2.5 The diagrams represent three experiments in...Ch. 14.3 - Prob. 1PPACh. 14.3 - Practice Problem BUILD
For the following general...Ch. 14.3 - Practice Problem CONCEPTUALIZE
Three initial-rate...Ch. 14.3 - The first-order decomposition of dinitrogen...Ch. 14.3 - The first-order decomposition of dinitrogen...Ch. 14.3 - 14.3.3 Consider the first-order reaction in which...Ch. 14.3 - Which figure below represents the numbers of...Ch. 14.3 - 14.3.5 Of the plots shown here, ___________...Ch. 14.4 - Practice Problem ATTEMPT
The rate constant for the...Ch. 14.4 - Practice Problem BUILD
Refer again to the reaction...Ch. 14.4 - Practice Problem CONCEPTUALIZE
The diagrams on...Ch. 14.4 - Use the table of data collected for a first-order...Ch. 14.4 - Prob. 2CPCh. 14.4 - Prob. 3CPCh. 14.5 - Practice Problem ATTEMPT Ethyl iodide ( C 2 H 5 I)...Ch. 14.5 - Practice Problem BUILD Use the calculated k from...Ch. 14.5 - Practice Problem CONCEPTUALIZE
Use the graph in...Ch. 14.5 - Use the following information to answer questions...Ch. 14.5 - Use the following information to answer questions...Ch. 14.5 - Use the following information to answer questions...Ch. 14.5 - 14.5.4 A plausible mechanism for the reaction:
Ch. 14.6 - Practice ProblemATTEMPT Calculate the half-life of...Ch. 14.6 - Practice ProblemBUILD Calculate the rate constant...Ch. 14.6 - Practice Problem CONCEPTUALIZE
The diagrams show a...Ch. 14.7 - Practice Problem ATTEMPT
The reaction is second...Ch. 14.7 - Practice Problem BUILD
Determine the initial...Ch. 14.7 - Practice ProblemCONCEPTUALIZE The diagrams below...Ch. 14.8 - Practice ProblemATTEMPT The second-order rate...Ch. 14.8 - Practice Problem BUILD Use the graph to determine...Ch. 14.8 - Prob. 1PPCCh. 14.9 - Practice ProblemATTEMPT Use the data in the...Ch. 14.9 - Practice ProblemBUILD Based on the data shown in...Ch. 14.9 - Practice Problem CONCEPTUALIZE
According to the...Ch. 14.10 - Practice ProblemATTEMPT Calculate the rate...Ch. 14.10 - Practice ProblemBUILD Calculate the rate constant...Ch. 14.10 - Practice ProblemCONCEPTUALIZE According to the...Ch. 14.11 - Practice Problem ATTEMPT
The reaction between and...Ch. 14.11 - Practice ProblemBUILD Propose a plausible...Ch. 14.11 - Practice Problem CONCEPTUALIZE
How many steps are...Ch. 14.12 - Practice Problem ATTEMPT
Show that the following...Ch. 14.12 - Practice Problem BUILD
The reaction proceeds via...Ch. 14.12 - Practice Problem CONCEPTUALIZE
The reaction of is...Ch. 14 - Prob. 1KSPCh. 14 - Prob. 2KSPCh. 14 - Prob. 3KSPCh. 14 - Prob. 4KSPCh. 14 - 14.1 What is meant by the rate of a chemical...Ch. 14 - Distinguish between average rate and instantaneous...Ch. 14 - What are the advantages of measuring the initial...Ch. 14 - Identify two reactions that are very slow (take...Ch. 14 - Write the reaction rate expressions for the...Ch. 14 - Write the reaction rate expressions for the...Ch. 14 - Consider the reaction: 2NO ( g ) + O 2 ( g ) → 2NO...Ch. 14 - 14.8 Consider the reaction:
Suppose that at a...Ch. 14 - 14.9 Explain what is meant by the rate law of a...Ch. 14 - Prob. 10QPCh. 14 - What are the units for the rate constants of...Ch. 14 - 14.12 Consider the zeroth-order reaction: a ...Ch. 14 - 14.13 The rate constant of a first-order reaction...Ch. 14 - Identify two reactions that are very slow (take...Ch. 14 - The rate law for the reaction: N H 4 + ( a q )+N O...Ch. 14 - Use the data in Table 14.2 to calculate the rate...Ch. 14 - 14.17 Consider the reaction:
From the following...Ch. 14 - Consider the reaction: X + Y → Z From the...Ch. 14 - Determine the overall orders of the reactions to...Ch. 14 - 14.20 Consider the reaction:
The rate of the...Ch. 14 - Cyclobutane decomposes to ethylene according to...Ch. 14 - The following gas-phase reaction was studied at...Ch. 14 - Write an equation relating the concentration of a...Ch. 14 - 14.24 Define half-life. Write the equation...Ch. 14 - Prob. 25QPCh. 14 - 14.26 For a first-order reaction, how long will it...Ch. 14 - What is the half-life of a compound if 75 percent...Ch. 14 - 14.28 The thermal decomposition of phosphine into...Ch. 14 - The rate constant for the second-order reaction:...Ch. 14 - The rate constant for the second-order reaction:...Ch. 14 - 14.31 The second-order rate constant for the...Ch. 14 - Prob. 32QPCh. 14 - 14.33 The reaction shown here follows first-order...Ch. 14 - 14 34 Define activation energy. What role does...Ch. 14 - Prob. 35QPCh. 14 - Prob. 36QPCh. 14 - The burning of methane in oxygen is a highly...Ch. 14 - Sketch a potential-energy versus reaction progress...Ch. 14 - The reaction H+H 2 → H 2 +H has been studied for...Ch. 14 - Over the range of about ±3°C from normal body...Ch. 14 - For the reaction: NO ( g ) + O 3 ( g ) → NO 2 ( g...Ch. 14 - The rate constant of a first-order reaction is 4...Ch. 14 - The rate constants of some reactions double with...Ch. 14 - 14.44 The rate at which tree crickets chirp is ...Ch. 14 - The rate of bacterial hydrolysis of fish muscle is...Ch. 14 - Prob. 46QPCh. 14 - Given the same reactant concentrations, the...Ch. 14 - 14.48 Variation of the rate constant with...Ch. 14 - 14.49 Diagram A describes the initial state of...Ch. 14 - 14 50 What do we mean by the mechanism of a...Ch. 14 - 14.51 What is an elementary step? What is the...Ch. 14 - 14.52 Classify the following elementary reactions...Ch. 14 - Reactions can be classified as unimolecular,...Ch. 14 - Determine the molecularity, and write the rate law...Ch. 14 - 14.55 What is the rate-determining step of a...Ch. 14 - 14.56 The equation for the combustion of ethane ...Ch. 14 - Specify which of the following species cannot be...Ch. 14 - Classify each of the following elementary steps as...Ch. 14 - 14.59 The rate law for the reaction:
is given by...Ch. 14 - For the reaction x 2 + y + z → x y + x z , it is...Ch. 14 - The rate law for the reaction: 2H 2 ( g ) + 2NO (...Ch. 14 - 14.62 The rate law for the decomposition of ozone...Ch. 14 - 14.63 How does a catalyst increase the rate of a...Ch. 14 - 14.64 What are the characteristics of a...Ch. 14 - A certain reaction is known to proceed slowly at...Ch. 14 - Most reactions, including enzyme-catalyzed...Ch. 14 - 14.67 Are enzyme-catalyzed reactions examples of...Ch. 14 - The concentrations of enzymes in cells are usually...Ch. 14 - When fruits such as apples and pears are cut. the...Ch. 14 - The first-order rate constant for the dehydration...Ch. 14 - Which two potential-energy profiles represent the...Ch. 14 - Consider the following mechanism for the...Ch. 14 - List four factors that influence the rate of a...Ch. 14 - 14.71 Suggest experimental means by which the...Ch. 14 - 14.75 “The rate constant for the reaction:
is .”...Ch. 14 - Prob. 76APCh. 14 - The following diagrams represent the progress of...Ch. 14 - The following diagrams show the progress of the...Ch. 14 - Prob. 79APCh. 14 - Prob. 80APCh. 14 - 14.81 When methyl phosphate is heated in acid...Ch. 14 - The rate of the reaction: CH 3 COOC 2 H 5 ( a q )...Ch. 14 - Explain why most metals used in catalysis are...Ch. 14 - Prob. 84APCh. 14 - The bromination of acetone is acid-catalyzed: CH 3...Ch. 14 - The decomposition of N 2 O to N 2 and O 2 is a...Ch. 14 - 14.87 The reaction proceeds slowly in aqueous...Ch. 14 - Prob. 88APCh. 14 - The integrated rate law for the zeroth-order...Ch. 14 - 14.90 A flask contains a mixture of compounds A...Ch. 14 - Prob. 91APCh. 14 - 14.92 The rate law for the reaction . Which of the...Ch. 14 - 14.93 The reaction of to form 2EG is exothermic,...Ch. 14 - 14.94 The activation energy for the decomposition...Ch. 14 - Prob. 95APCh. 14 - 14.96 When 6 g of granulated Zn is added to a...Ch. 14 - Prob. 97APCh. 14 - 14.98 A certain first-order reaction is 35.5...Ch. 14 - 14.99 The decomposition of dinitrogen pentoxide...Ch. 14 - 14.100 The thermal decomposition of obeys...Ch. 14 - 14.101 When a mixture of methane and bromine is...Ch. 14 - 14.102 The rate of the reaction between to form...Ch. 14 - The rate constant for the gaseous reaction: H 2 (...Ch. 14 - A gas mixture containing CH 3 fragments. C 2 H 6...Ch. 14 - Consider the following elementary step: X + 2Y →...Ch. 14 - 14.106 The following scheme in which A is...Ch. 14 - 14.107 (a) Consider two reactions, A and B. If the...Ch. 14 - The rate law for the following reaction: CO ( g )...Ch. 14 - Consider the following elementary steps for a...Ch. 14 - Prob. 110APCh. 14 - Consider the following potential-energy profile...Ch. 14 - The rate of a reaction was followed by the...Ch. 14 - 14.113 The first-order rate constant for the...Ch. 14 - 14.114 Many reactions involving heterogeneous...Ch. 14 - Thallium(I) is oxidized by cerium(IV) as follows:...Ch. 14 - The activation energy for the reaction: N 2 O ( g...Ch. 14 - Δ H ° for the reaction in Problem 14.116 is -164...Ch. 14 - 14.118 At a certain elevated temperature, ammonia...Ch. 14 - 14.119 The following expression shows the...Ch. 14 - In a certain industrial process involving a...Ch. 14 - Strontium-90, a radioactive isotope, is a major...Ch. 14 - Prob. 122APCh. 14 - Prob. 123APCh. 14 - A factory that specializes in the refinement of...Ch. 14 - 14.125 When the concentration of A in the reaction...Ch. 14 - 14.126 The activity of a radioactive sample is the...Ch. 14 - Prob. 127APCh. 14 - Prob. 128APCh. 14 - Prob. 129APCh. 14 - Prob. 130APCh. 14 - Prob. 131APCh. 14 - Prob. 132APCh. 14 - Prob. 133APCh. 14 - 14.134 At a certain elevated temperature, ammonia...Ch. 14 - Polyethylene is used in many items, including...Ch. 14 - In recent years, ozone in the stratosphere has...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
- Indicate whether the product of the reaction between Naphthalene and CrO3 in acetic acid at 25ºC is 1,4 naphthoquinone or phthalic anhydride.arrow_forwardIndicate the products of the reaction between CH3COCH2COOC2H5 and Na+-OC2H5.arrow_forwardPrimary, Secondary, and Tertiary Alcohols O-H O-H O-H R₁-C-H R₁-C-H R₁-C-R₁ H R₂ R₂ Primary Alcohol Secondary Alcohol ChemistryLearner.com R stands for Carbon group like ethyl methyl propyl Tertiary Alcohol If 1 carbon group with two H attached to alcoholic carbon, then primary If 2 carbon group and 1 H are attached to alcoholic carbon, then secondary IF 3 carbon group and no H attach to alcoholic carbon then tertiary. The bottom line Starting "Weak" oxidant material PCC, DMP, Swern, etc Primary alcohol Aldehyde OH Secondary alcohol Ketone OH "Strong" oxidant KMnO4, H₂CrO4 (or equivalent) OH Carboxylic acid 요 Ketone No reaction No reaction Tertiary alcohol 1. Is ethanol a primary, secondary, or tertiary alcohol? Write out the structures of ethanol and any oxidation products of ethanol. If there is more than one oxidation product, give the structure of each of the products. 2. Is 2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-propanol and any…arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Kinetics: Chemistry's Demolition Derby - Crash Course Chemistry #32; Author: Crash Course;https://www.youtube.com/watch?v=7qOFtL3VEBc;License: Standard YouTube License, CC-BY