(a)
Interpretation:
The common names of the acid chloride and carboxylate anion reactants and acid anhydride products have to be written.
Concept Introduction:
Naming of Acid Chloride:
Acid chlorides are derivatives of carboxylic acids with the formula,
Acid chlorides are named by replacing the –ic acid ending of the common name with –yl chloride and –oic acid ending of the IUPAC name of the
Naming of Acid Anhydrides:
Acid anhydrides are compounds with the formula,
Acid anhydride is divided into symmetrical and unsymmetrical anhydrides.
Symmetrical anhydrides: contain same acyl groups. They are named by replacing acid ending of the carboxylic acid with the word anhydride.
Unsymmetrical anhydrides: contain different acyl groups. They are named by arranging the names of two-parent carboxylic acid followed by the word anhydride. The names of the carboxylic acid are arranged by size or in alphabetical order.
(b)
Interpretation:
The common names of the acid chloride and carboxylate anion reactants and acid anhydride products have to be written.
Concept Introduction:
Naming of Acid Chloride:
Acid chlorides are derivatives of carboxylic acids with the formula,
Acid chlorides are named by replacing the –ic acid ending of the common name with –yl chloride and –oic acid ending of the IUPAC name of the carboxylic acid with –oyl chloride.
Naming of Acid Anhydrides:
Acid anhydrides are compounds with the formula,
Acid anhydride is divided into symmetrical and unsymmetrical anhydrides.
Symmetrical anhydrides: contain same acyl groups. They are named by replacing acid ending of the carboxylic acid with the word anhydride.
Unsymmetrical anhydrides: contain different acyl groups. They are named by arranging the names of two-parent carboxylic acid followed by the word anhydride. The names of the carboxylic acid are arranged by size or in alphabetical order.
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Chapter 14 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
- Write the calculate the reaction quotient for the following system, if the partial pressure of all reactantsand products is 0.15 atm: NOCl (g) ⇌ NO (g) + Cl2 (g) H = 20.5 kcalarrow_forwardComplete the spectroscopy with structurearrow_forwardcould you answer the questions and draw the complete mechanismarrow_forward
- Complete the spectroscopy with structurearrow_forwardCalculate the reaction quotient for the reaction:NaOH (s) ⇌ Na+ (aq)+ OH- (aq) + 44.4 kJ [Na+] = 4.22 M [OH-] = 6.41 Marrow_forwardGiven the following concentrations for a system, calculate the value for the reaction quotient: Cl2(g)+ CS2(g) ⇌ CCl4(g)+ S2Cl2(g) Cl2 = 31.1 atm CS2 = 91.2 atm CCl4 = 2.12 atm S2Cl2 = 10.4 atmarrow_forward
- Match each chemical or item with the proper disposal or cleanup mwthod, Not all disposal and cleanup methods will be labeled. Metal sheets C, calcium, choroide solutions part A, damp metal pieces Part B, volumetric flask part A. a.Return to correct lables”drying out breaker. Place used items in the drawer.: Rinse with deionized water, dry as best you can, return to instructor. Return used material to the instructor.: Pour down the sink with planty of running water.: f.Pour into aqueous waste container. g.Places used items in garbage.arrow_forwardWrite the equilibrium constant expression for the following reaction: HNO2(aq) + H2O(l) ⇌ H3O+(aq) + NO2-(aq)arrow_forwardWrite the reaction quotient for: Pb2+(aq) + 2 Cl- (aq) ⇌ PbCl2(s)arrow_forward
- Write the equilibrium constant expression for the following system at equilibrium: I2 (g) ⇌ 2 I (g)arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardWe learned four factors (ARIO) for comparing the relative acidity of compounds. When two of these factors are in competition, the order of priority is the order in which these factors were covered ("atom" being the most important factor and "orbital" being the least important). However, we also mentioned that there are exceptions to this order of priority. Compare the two compounds and identify the exception. OH PK-4.75 SH PK-10.6 5. "Resonance" is more important than "atom" because the conjugate base of first compound is more stable than the second. "Atom" is more important than "resonance" because the conjugate base of first compound is more stable than the second. "Resonance" is more important than "atom" because the conjugate base of second compound is more stable than the first. "Atom" is more important than "resonance" because the conjugate base of second compound is more stable than the first.arrow_forward
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