Principles of General Organic & Biological Chemistry
Principles of General Organic & Biological Chemistry
2nd Edition
ISBN: 9780077633721
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 14.2, Problem 14.7P

a.

Interpretation Introduction

Interpretation:

Chiral centers in the given monosaccharide has to be labelled, the monosaccharide has to be classified as D or L and also the enantiomer of the given monosaccharide has to be drawn.

Principles of General Organic & Biological Chemistry, Chapter 14.2, Problem 14.7P , additional homework tip  1

Concept Introduction:

A carbon atom that is bonded to four different groups is known as a chiral carbon atom.  This can rotate the plane polarized light.  D- and L- isomers of monosaccharide can be identified by looking into the chiral center that is farther from the carbonyl group.  In a Fischer projection, if the OH group is present on the right side in the chiral center that is farthest from the carbonyl group means it is a D monosaccharide and if the OH group is present on the left side means it is a L monosaccharide.

Enantiomers are two stereoisomers of a compound that rotate the plane polarized light exactly opposite.  The configuration present in the enantiomers will be exactly opposite to each other.

b.

Interpretation Introduction

Interpretation:

Chiral centers in the given monosaccharide has to be labelled, the monosaccharide has to be classified as D or L and also the enantiomer of the given monosaccharide has to be drawn.

Principles of General Organic & Biological Chemistry, Chapter 14.2, Problem 14.7P , additional homework tip  2

Concept Introduction:

Refer part “a.”.

c.

Interpretation Introduction

Interpretation:

Chiral centers in the given monosaccharide has to be labelled, the monosaccharide has to be classified as D or L and also the enantiomer of the given monosaccharide has to be drawn.

Principles of General Organic & Biological Chemistry, Chapter 14.2, Problem 14.7P , additional homework tip  3

Concept Introduction:

Refer part “a.”.

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