Principles of General Organic & Biological Chemistry
Principles of General Organic & Biological Chemistry
2nd Edition
ISBN: 9780077633721
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 14, Problem 14.39AP

a.

Interpretation Introduction

Interpretation:

Monosaccharides that are stereoisomers has to be identified from monosaccharides A, B, and C.

Concept Introduction:

Stereoisomers of a compounds are the ones that have the same structural formula but different configuration at the chiral center.  They rotate the plane polarized light.

b.

Interpretation Introduction

Interpretation:

Monosaccharides that are consititutional isomers has to be identified from monosaccharides A, N, and C.

c.

Interpretation Introduction

Interpretation:

Enantiomer of structure B has to be drawn.

Concept Introduction:

Enantiomers are two stereoisomers of a compound that rotate the plane polarized light exactly opposite.  The configuration present in the enantiomers will be exactly opposite to each other.

d.

Interpretation Introduction

Interpretation:

Fischer projection for structure A has to be drawn.

Concept Introduction:

Fischer projection formula simply uses cross for representing tetrahedral carbon atom.  The carbon atom that is present in the intersection point in cross.  The horizontal bonds means they are coming forward and they are present on wedge bond.  The vertical bonds means they are pointing away and they are present on dashed lines.

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43) 10.00 ml of vinegar (active ingredient is acetic acid) is titrated to the endpoint using 19.32 ml of 0.250 M sodium hydroxide. What is the molarity of acetic acid in the vinegar? YOU MUST SHOW YOUR WORK. NOTE: MA x VA = MB x VB
424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)
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Chapter 14 Solutions

Principles of General Organic & Biological Chemistry

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