The authenticity of the given statement, “The rate law for the reaction must be Rate = k [ A ] [ B ] ”.

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Answer 1

Question

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

C. NaOMe, Br Br

Answer 2

Question

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

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Answer 3

Question

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

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Answer 4

Question

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

Answer 6

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

Answer 7

Chapter 14, Problem 89AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

Answer 8

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

Answer 9

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

Answer 10

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

Answer 11

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

Answer 12

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

Answer 13

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14.2 - If the experiment in Figure 14.2 is run for 60 s,...Ch. 14.2 - Prob. 14.1.2PE Ch. 14.2 - Which of the following could be the instantaneous...Ch. 14.2 - Using Figure 14.3, determine the instantaneous...Ch. 14.2 - At a certain time in a reaction, substance A is...Ch. 14.2 - Prob. 14.3.2PE Ch. 14.3 - Suppose the rate law for the reaction in this...Ch. 14.3 - Assuming that rate = k[A][B], rank the mixtures...Ch. 14.3 - Prob. 14.5.1PE Ch. 14.3 - Prob. 14.5.2PE

The authenticity of the given statement, “The rate law for the reaction must be Rate = k [ A ] [ B ] ”.

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To determine: The authenticity of the given statement, “The rate law for the reaction must be Rate=k[A][B] ”.

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law is second order”.

To determine: The authenticity of the given statement, “If the reaction is an elementary reaction, the rate law of reverse reaction is first order”.

To determine: The authenticity of the given statement, “The activation energy for the reverse reaction must be greater than that for the forward reaction”.

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Chapter 14 Solutions